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Concept
Isotope hydrology
Summary
Isotope hydrology is a field of geochemistry and hydrology that uses naturally occurring stable and radioactive isotopic techniques to evaluate the age and origins of surface and groundwater and the processes within the atmospheric hydrologic cycle. Isotope hydrology applications are highly diverse, and used for informing water-use policy, mapping aquifers, conserving water supplies, assessing sources of water pollution, and increasingly are used in eco-hydrology to study human impacts on all dimensions of the hydrological cycle and ecosystem services.
Water molecules carry unique isotopic "fingerprints", based in part on differing ratios of the oxygen and hydrogen isotopes that constitute the water molecule. Isotopes are atoms of the same element that have a different number of neutrons in their nuclei.
Air, freshwater and seawater contain mostly oxygen-16 ( 16O). Oxygen-18 (18O) occurs in approximately one oxygen atom in every five hundred and has a slightly higher mass than oxygen-16, as it has two extra neutrons. From a simple energy and bond breakage standpoint this results in a preference for evaporating the lighter 16O containing water and leaving more of the 18O water behind in the liquid state (called isotope fractionation). Thus seawater tends to contain more 18O than rain and snow.
Dissolved ions in surface and groundwater water also contain useful isotopes for hydrological investigations. Dissolved species like sulfate and nitrate contain differing ratios of 34-S to 32-S or 15-N to 14-N, and are often diagnostic of pollutant sources. Natural radioisotopes like tritium (3-H) and radiocarbon (14-C) are also used as natural clocks to determine the residence times of water in aquifers, rivers, and the oceans.
The most commonly used isotope application in hydrology uses hydrogen and oxygen isotopes to evaluate sources or age of water, ice or snow. Isotopes in ice cores help to reveal conditions of past climate.
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In hydrogeology, groundwater flow is defined as the "part of streamflow that has infiltrated the ground, entered the phreatic zone, and has been (or is at a particular time) discharged into a stream channel or springs; and seepage water." It is governed by the groundwater flow equation. Groundwater is water that is found underground in cracks and spaces in the soil, sand and rocks. Where water has filled these spaces is the phreatic (also called) saturated zone.
Subsurface flow
Subsurface flow, in hydrology, is the flow of water beneath earth's surface as part of the water cycle. In the water cycle, when precipitation falls on the earth's land, some of the water flows on the surface forming streams and rivers. The remaining water, through infiltration, penetrates the soil traveling underground, hydrating the vadose zone soil, recharging aquifers, with the excess flowing in subsurface runoff. In hydrogeology it is measured by the Groundwater flow equation.
Hydrology
Hydrology () is the scientific study of the movement, distribution, and management of water on Earth and other planets, including the water cycle, water resources, and drainage basin sustainability. A practitioner of hydrology is called a hydrologist. Hydrologists are scientists studying earth or environmental science, civil or environmental engineering, and physical geography. Using various analytical methods and scientific techniques, they collect and analyze data to help solve water related problems such as environmental preservation, natural disasters, and water management.