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Concept
Solubility equilibrium
Summary
Solubility equilibrium is a type of dynamic equilibrium that exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The solid may dissolve unchanged, with dissociation, or with chemical reaction with another constituent of the solution, such as acid or alkali. Each solubility equilibrium is characterized by a temperature-dependent solubility product which functions like an equilibrium constant. Solubility equilibria are important in pharmaceutical, environmental and many other scenarios.
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another. When equilibrium is established and the solid has not all dissolved, the solution is said to be saturated. The concentration of the solute in a saturated solution is known as the solubility. Units of solubility may be molar (mol dm−3) or expressed as mass per unit volume, such as μg mL−1. Solubility is temperature dependent. A solution containing a higher concentration of solute than the solubility is said to be supersaturated. A supersaturated solution may be induced to come to equilibrium by the addition of a "seed" which may be a tiny crystal of the solute, or a tiny solid particle, which initiates precipitation.
There are three main types of solubility equilibria.
Simple dissolution.
Dissolution with dissociation reaction. This is characteristic of salts. The equilibrium constant is known in this case as a solubility product.
Dissolution with ionization reaction. This is characteristic of the dissolution of weak acids or weak bases in aqueous media of varying pH.
In each case an equilibrium constant can be specified as a quotient of activities. This equilibrium constant is dimensionless as activity is a dimensionless quantity.
Official source
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