Time Estimation of Polymer Translocation through Nano-Membrane

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Enabling simultaneous reprocessability and fire protection via incorporation of phosphine oxide monomer in epoxy vitrimer

The conception of epoxy thermosets with both reprocessability and flame retardancy delineates a new horizon in polymer science, offering a material solution that is not only superior in fire safety but is also environment friendly. Herein, a flame-retardan ...

Journal Mater Sci Technol2024

Influence of structural dynamics on cell uptake investigated with single-chain polymeric nanoparticles

Francesco Stellacci, Arthur Eliot Bouchez, Lixia Wei, Suiyang Liao

Most nanoparticles' parameters affect their interactions with cells. To date, all the parameters studied are basically static (e.g., size, shape, ligands, and charge). This is unfortunate, because proteins have struc-tural dynamics that most nanoparticles ...

CELL PRESS2023

Incorporation of Lignin in Bio-Based Resins for Potential Application in Fiber-Polymer Composites

Mário Alexandre De Jesus Garrido, Mateus De Assunção Hofmann

Bio-based resins, obtained from renewable raw materials, are a more sustainable alternative to oil-based resins for fiber-reinforced polymer (FRP) composites. The incorporation of lignin in those resins has the potential to enhance their performance. This ...

MDPI2023

Acetal-Stabilized Carbohydrates as Novel Platform Molecules for Renewable Polymer Production

Lorenz Perry Manker

To address the rising demand for plastics, it is essential to create new types of polymers that are both highly recyclable and emit minimal amounts of greenhouse gases. These plastics should be derived from readily available, renewable feedstocks. Such eff ...

EPFL2023

Phase behaviour and structure of a model biomolecular condensate

Julian Charles Shillcock

Phase separation of immiscible fluids is a common phenomenon in polymer chemistry, and is recognized as an important mechanism by which cells compartmentalize their biochemical reactions. Biomolecular condensates are condensed fluid droplets in cells that ...

2020

Density effects on nanoparticle transport in the hyporheic zone

David Andrew Barry, Ho Ling Li, Qihao Jiang

A carbon solution composed of nanoparticles was used in experiments designed to explore nanoparticle transport characteristics within the hyporheic zone of a riverbed. Experiments and numerical simulations demonstrated that nanoparticle transport in the hy ...

2018

Using SAS functions and high-resolution isotope data to unravel travel time distributions in headwater catchments

Andrea Rinaldo, Paolo Benettin, Gianluca Botter

We use high-resolution tracer data from an experimental site to test theoretical approaches that integrate catchment-scale flow and transport processes in a unified framework centered on selective age sampling by streamflow and evapotranspiration fluxes. T ...

American Geophysical Union2017

Physically Based Modeling of Shear Modulus-Temperature Relationship for Thermosets

Thomas Keller, Anastasios Vassilopoulos, Wei Sun

A new physically based model for the simulation of the imaginary part of the shear modulus-temperature (G ''-T) curve of thermosets is introduced in this paper. The model is based on the modification of the G ''-T equation used for thermoplastic polymers v ...

Wiley-Blackwell2015

Storage selection functions: A coherent framework for quantifying how catchments store and release water and solutes

Andrea Rinaldo, Paolo Benettin, Enrico Bertuzzo, Gianluca Botter

We discuss a recent theoretical approach combining catchment-scale flow and transport processes into a unified framework. The approach is designed to characterize the hydrochemistry of hydrologic systems and to meet the challenges posed by empirical eviden ...

Amer Geophysical Union2015

Theory of percolation and tunneling regimes in nanogranular metal films

Claudio Grimaldi

Nanogranular metal composites, consisting of immiscible metallic and insulating phases deposited on a substrate, are characterized by two distinct electronic transport regimes depending on the relative amount of the metallic phase. At sufficiently large me ...

Amer Physical Soc2014

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Enabling simultaneous reprocessability and fire protection via incorporation of phosphine oxide monomer in epoxy vitrimer

Véronique Michaud, Valentin Rougier

Journal Mater Sci Technol2024