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Extent Computation under Rank-deficient Conditions

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The influence of sulfate addition on hydration kinetics and C-S-H morphology of C3S and C3S/C(3)A systems

Karen Scrivener, Franco Alberto Zunino Sommariva

A comprehensive understanding of hydration kinetics, sulfate requirement and phase assemblage of Portland cement is crucial for further optimization of early-age performance, especially when part of cement is replaced by mineral additions in blended cement ...

Pergamon-Elsevier Science Ltd2022

A Prony-based approach for accelerating the lightning electromagnetic fields computation above a perfectly conducting ground

Farhad Rachidi-Haeri, Marcos Rubinstein

Lightning strikes can seriously affect the reliability and availability of electrical infrastructures. The computation of lightning-electromagnetic fields represents one of the most crucial steps in the evaluation of the induced effects; thus, having at di ...

Elsevier2022

A spectroscopic inference and SOLPS-ITER comparison of flux-resolved edge plasma parameters in detachment experiments on TCV

Basil Duval, Holger Reimerdes, Christian Gabriel Theiler, Artur Perek, Kevin Henricus Annemarie Verhaegh, Mirko Wensing

This work presents the use of a collisional-radiative model to infer plasma parameters from 2D emissivities of several deuterium Balmer lines. The emissivities were obtained by MANTIS, an absolutely calibrated, ten-camera imaging polychromator with

IOP Publishing Ltd2022

(4+3) Annulation of Donor-Acceptor Cyclopropanes and Azadienes: Highly Stereoselective Synthesis of Azepanones

Jérôme Waser, Stefano Nicolai

Azepanes are important seven-membered heterocycles, which are present in numerous natural and synthetic compounds. However, the development of convergent synthetic methods to access them remains challenging. Herein, we report the Lewis acid catalyzed (4+3) ...

Wiley-VCH Verlag GmbH2022

Emergent thermophoretic behavior in chemical reaction systems

Paolo De Los Rios, Shiling Liang, Daniel Maria Busiello

Exposing a solution to a temperature gradient can lead to the accumulation of particles on either the cold or warm side. This phenomenon is known as thermophoresis, and its microscopic origin is still debated. Here, we show that thermophoresis can be obser ...

IOP Publishing Ltd2022

Computational Concepts for Reconstructing and Simulating Brain Tissue

Srikanth Ramaswamy, Felix Schürmann, Jean-Denis Georges Emile Courcol

It has previously been shown that it is possible to derive a new class of biophysically detailed brain tissue models when one computationally analyzes and exploits the interdependencies or the multi-modal and multi-scale organization of the brain. These re ...

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Modulating the Reactivity of Liquid Ga Nanoparticle Inks by Modifying Their Surface Chemistry

Raffaella Buonsanti, Laia Castilla Amorós, James Richard Pankhurst, Tzu-Chin Chang Chien

Micro- and nanosized particles of liquid metals, particularly Ga-based alloys, are attracting increasing attention for applications in several fields. The surface functionalization of Ga-based nanoparticles (NPs) with organic ligands renders easily process ...

2022

Study of He/Ne+Ar, Kr, N2, H2, D2 Chemi-Ionization Reactions by Electron Velocity-Map Imaging

Andreas Osterwalder, Sean Dennis Steven Gordon, Junwen Zou, Silvia Tanteri

The chemi-ionization of Ar, Kr, N2, H2, and D2 by Ne(3P2) and of Ar, Kr, and N2 by He(3S1) was studied by electron velocity map imaging (e-VMI) in a crossed molecular beam experiment. A curved magnetic hexapole was used to state-select the metastable speci ...

2021

Molecular Volcano Plots: Tools for Rationalizing and Predicting the Performance of Homogeneous Catalysts

Boodsarin Sawatlon

The generation of catalyst design tools is important for developing both economically and environmentally friendly reactions. This thesis focuses on the use and development of such a tool, molecular volcano plots, which have the ability to estimate catalyt ...

EPFL2021

Development of free-boundary equilibrium and transport solvers for simulation and real-time interpretation of tokamak experiments

Francesco Carpanese

To exploit fusion as a source of energy, a hot and dense confined plasma is needed. This is achieved in tokamaks by actively controlling the plasma state meaning shape, position and internal kinetic profiles. This thesis addresses two topics: the developme ...

EPFL2021

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A spectroscopic inference and SOLPS-ITER comparison of flux-resolved edge plasma parameters in detachment experiments on TCV

Basil Duval, Holger Reimerdes, Christian Gabriel Theiler, Artur Perek, Kevin Henricus Annemarie Verhaegh, Mirko Wensing

IOP Publishing Ltd2022

A Prony-based approach for accelerating the lightning electromagnetic fields computation above a perfectly conducting ground

Farhad Rachidi-Haeri, Marcos Rubinstein

Elsevier2022

Computational Concepts for Reconstructing and Simulating Brain Tissue

Srikanth Ramaswamy, Felix Schürmann, Jean-Denis Georges Emile Courcol

Springer2022

Development of free-boundary equilibrium and transport solvers for simulation and real-time interpretation of tokamak experiments

Francesco Carpanese

EPFL2021