Improvements in Resolution of 1H NMR of Solids

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Pure Isotropic Proton Solid State NMR

David Lyndon Emsley, Pinelopi Moutzouri, Daria Torodii, Bruno Simões de Almeida

Resolution in proton solid state magic angle sample spinning (MAS) NMR is limited by the intrinsically imperfect nature of coherent averaging induced by either MAS or multiple pulse sequence methods. Here, we suggest that instead of optimizing and perfecti ...

2021

Nanoscale Phase Segregation in Supramolecular π-Templating for Hybrid Perovskite Photovoltaics from NMR Crystallography

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Ursula Röthlisberger, Jovana Milic, Marko Mladenovic, Ulf Anders Hagfeldt, Dominik Józef Kubicki, Yuhang Liu, Michael Allan Hope

The use of layered perovskites is an important strategy to improve the stability of hybrid perovskite materials and their optoelectronic devices. However, tailoring their properties requires accurate structure determination at the atomic scale, which is a ...

2021

Homonuclear Decoupling in H-1 NMR of Solids by Remote Correlation

David Lyndon Emsley, Gabriele Stevanato, Pinelopi Moutzouri, Federico Maria Paruzzo, Bruno Simões de Almeida

The typical linewidths of H-1 NMR spectra of powdered organic solids at 111 kHz magic-angle spinning (MAS) are of the order of a few hundred Hz. While this is remarkable in comparison to the tens of kHz observed in spectra of static samples, it is still th ...

Wiley-VCH Verlag GmbH2020

Glutamine-to-glutamate ratio in the nucleus accumbens predicts effort-based motivated performance in humans

Rolf Gruetter, Maria del Carmen Sandi Perez, Lijing Xin, Alina Veronika Irene Strasser, Gediminas Luksys

Substantial evidence implicates the nucleus accumbens in motivated performance, but very little is known about the neurochemical underpinnings of individual differences in motivation. Here, we applied 1H magnetic resonance spectroscopy (1H-MRS) at ultra-hi ...

2020

Hyperpolarization via dissolution dynamic nuclear polarization: new technological and methodological advances

Andrea Capozzi, Arthur César Pinon

Dissolution-DNP is a method to boost liquid-state NMR sensitivity by several orders of magnitude. The technique consists in hyperpolarizing samples by solid-state dynamic nuclear polarization at low temperature and moderate magnetic field, followed by an i ...

SPRINGER2021

Kinetics of mixing-water repartition in UHPFRC paste and its effect on hydration and microstructural development

Eugen Brühwiler, Karen Scrivener, Emmanuel Denarié, Arnaud Charles Albert Muller, Mohammadhadi Kazemi Kamyab

The hydration of an ultra-high performance fibre reinforced concrete (UHPFRC) paste with a water to cement ratio of 0.18 was followed by proton nuclear magnetic resonance (1H NMR) alongside more classical techniques for hydration kinetics, and microstructu ...

Pergamon-Elsevier Science Ltd2019

One- and Two-Dimensional High-Resolution NMR from Flat Surfaces

David Lyndon Emsley, Aaron James Rossini, Brennan James Walder

Determining atomic-level characteristics of molecules on two-dimensional surfaces is one of the fundamental challenges in chemistry. High-resolution nuclear magnetic resonance (NMR) could deliver rich structural information, but its application to two-dime ...

AMER CHEMICAL SOC2019

Upgrade of a low-temperature scanning tunneling microscope for electron-spin resonance

Harald Brune, François Patthey, Nicolas Weiss, Donat Fabian Natterer, Tobias Bilgeri, Patrick Robert Forrester

Electron spin resonance with a scanning tunneling microscope (ESR-STM) combines the high energy resolution of spin resonance spectroscopy with the atomic scale control and spatial resolution of STM. Here we describe the upgrade of a helium-3 STM with a 2D ...

AMER INST PHYSICS2019

Broadband single-chip transceivers for compact NMR probes

Marco Grisi

Nuclear magnetic resonance (NMR) is one of the most relevant spectroscopic tools in use today. However, NMR requires relatively expensive and complicated experimental settings given by the combination of high homogeneous magnetic fields and a relatively co ...

EPFL2017

Direct enhancement of nitrogen-15 targets at high-field by fast ADAPT-SABRE

Gabriele Stevanato

Signal Amplification by Reversible Exchange (SABRE) is an attractive nuclear spin hyperpolarization technique capable of huge sensitivity enhancement in nuclear magnetic resonance (NMR) detection. The resonance condition of SABRE hyperpolarization depends ...

Academic Press Inc - Elsevier Science2017

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