Publication
The anodic methoxylation of formaldehyde dimethylacetal (FADMA) to trimethylorthoformate (TMOF) in basic methanol was investigated on boron-doped diamond (BDD) electrodes. Cyclic voltammetry and preparative electrolysis have shown that FADMA is electrochem. inactive in the solvent stability region; nevertheless FADMA can be oxidized in the potential region of methanol oxidn. A reaction scheme involving intermediates of methanol oxidn. (methoxy radicals) has been proposed. [on SciFinder (R)]
Ardemis Anoush Boghossian, Melania Reggente, Mohammed Mouhib, Fabian Fischer, Hanxuan Wang, Charlotte Elisabeth Marie Roullier, Patricia Brandl
Jan Van Herle, Suhas Nuggehalli Sampathkumar, Khaled Lawand, Zoé Mury
Sophia Haussener, Isaac Thomas Holmes-Gentle, Roberto Valenza, Franky Esteban Bedoya Lora