Organic chemistry is essential for the development of a modern society and technical progress requires the continuous development of synthetic methodologies Novel, efficient, selective and flexible protocols are employed to access complex frameworks from s ...
The performance of rhodium complex [Cp*Rh(bis(pyrazol-1-yl)methane)Cl]Cl was evaluated for formic acid dehydrogenation in aqueous solution. Solid-state X-ray diffraction helped to confirm the catalyst structure. Multinuclear NMR spectroscopy was employed t ...
We report the first decarboxylative alkynylation of the C-terminus of peptides starting from free carboxylic acids. The reaction is fast, metal-free, and proceeds cleanly to afford alkynylated peptides with a broad tolerance for the C-terminal amino acid. ...
A multifiltration is a functor indexed by Nr that maps any morphism to a monomorphism. The goal of this paper is to describe in an explicit and combinatorial way the natural Nr-graded R[x(1),...x(r)]-module structure on the homology of a multifiltration of ...
Transition-metal catalyzed C-H functionalizations have impacted and changed synthetic approaches towards the construction of relevant complex molecules, comprising natural products, active pharmaceutical ingredients, and organic materials. This thesis desc ...
As technology advances, surface coatings become more and more important to assure materials performances. In recent years, molecular coatings have found larger acceptance and uses. Among them, self-assembled monolayers (SAMs) are attractive because they ar ...
We propose and analyse a new discontinuous reduced basis element method for the approximation of parametrized elliptic PDEs in partitioned domains. The method is built upon an offline stage (parameter independent) and an online (parameter dependent) one. I ...
Sulfoximines with stereogenic sulfur atoms are attractive structural motifs in drug discovery. A direct catalytic enantioselective method for the synthesis of sulfur-chiral 1,2-benzothiazines from readily accessible diaryl sulfoximines is presented. Rhodiu ...
Splines come in a variety of flavors that can be characterized in terms of some differential operator L. The simplest piecewise-constant model corresponds to the derivative operator. Likewise, one can extend the traditional notion of total variation by con ...
Let R be a unital commutative ring, and let M be an R-module that is generated by k elements but not less. Let be the subgroup of generated by the elementary matrices. In this paper we study the action of by matrix multiplication on the set of unimodular r ...
