Publications related to Engineering polymers with improved charge transport properties from bithiophene-containing polyamides

Supramolecular Modifications of Semicrystalline Polymers

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

EPFL2023

Incorporation of Lignin in Bio-Based Resins for Potential Application in Fiber-Polymer Composites

Mário Alexandre De Jesus Garrido, Mateus De Assunção Hofmann

Bio-based resins, obtained from renewable raw materials, are a more sustainable alternative to oil-based resins for fiber-reinforced polymer (FRP) composites. The incorporation of lignin in those resins has the potential to enhance their performance. This ...

MDPI2023

Recyclable flame retardant phosphonated epoxy based thermosets enabled via a reactive approach

Véronique Michaud, Valentin Rougier

The development of reusable fire-safe polymers with a prolonged lifetime heralds the switch for a transition towards circular economy. In this framework, we report a novel phosphonated thermoset which is composed of networked phosphonate esters containing ...

ELSEVIER SCIENCE SA2023

Sustainable polyesters via direct functionalization of lignocellulosic sugars

François Maréchal, Harm-Anton Klok, Véronique Michaud, Jeremy Luterbacher, Yves Leterrier, Maxime Alexandre Clément Hedou, Adrien Julien Demongeot, Graham Reid Dick, Christèle Rayroud, Thibault Rambert

The development of sustainable plastics from abundant renewable feedstocks has been limited by the complexity and efficiency of their production, as well as their lack of competitive material properties. Here we demonstrate the direct transformation of the ...

2022

Competing Effects of Hydration and Cation Complexation in Single-Chain Alginate

Alginic acid, a naturally occurring anionic polyelectrolyte, forms strong physically cross-linked hydrogels in the presence of metal cations. The latter engage in electrostatic interactions that compete with intra- and intermolecular hydrogen bonds, determ ...

American Chemical Society2022

Semiaromatic polyamides with enhanced charge carrier mobility

John Christopher Plummer, Holger Frauenrath, Nicolas Candau

The control of local order in polymer semiconductors using non-covalent interactions may be used to engineer materials with interesting combinations of mechanical and optoelectronic properties. To investigate the possibility of preparing n-type polymer sem ...

ROYAL SOC CHEMISTRY2021

Revisiting Cation Complexation and Hydrogen Bonding of Single-Chain Polyguluronate Alginate

Modifying the properties of bio-based materials has garnered increasing interest in recent years. In related applications, the ability of alginates to complex with metal ions has been shown to be effective in liquid-to-gel transitions, useful in the develo ...

American Chemical Society2021

Resin Transfer molding of High-Fluidity Polyamide-6 with modified Glass-Fabric preforms

Véronique Michaud, Damiano Salvatori, Baris Çaglar, Robin Samuel Trigueira, Colin Gomez

In Resin Transfer Molding (RTM), resin precursors of thermoset or, more recently, thermoplastic polymers are generally employed, raising issues related to the chemical reaction taking place during and after part processing. In this study, already polymeriz ...

2021

Nature-inspired Circular-economy Recycling (NaCRe) for Proteins

Simone Giaveri

Since a few decades our planet has been loaded with billion tons of synthetic polymer-based materials, commonly named plastics. The large scale of plastic production, associated with its limited recyclability, are the driving force for the accumulation of ...

EPFL2021

Hydrogen-Bonded Small Molecules and Polymers in Organic Electronics

Bilal Özen

Organic semiconductors are important components for applications in different fields of technology, as their advantages include the possibility of low-temperature processing as well as low-cost, large-area manufacturing based on solution-based processes, c ...

EPFL2020