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Simulation tool for variably saturated flow with comprehensive geochemical reactions in two and three-dimensional domains

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Global Mapping of Potential and Climatic Plant‐Available Soil Water

The estimation of plant-available soil water (PASW) is essential to quantify transpiration fluxes, the onset of heatwaves, irrigation water management, land-use decisions, vegetation ecology, and land surface memory in climate models. PASW is the amount of ...

2023

Spatially Explicit Linkages Between Redox Potential Cycles and Soil Moisture Fluctuations

Andrea Rinaldo, Rizlan Bernier-Latmani, Paolo Benettin, Manon Frutschi, Simiao Wang, Filippo Miele, Mitra Asadollahi

Reduction-oxidation cycles measured through soil redox potential (Eh) are associated with dynamic soil microbial activity. Understanding changes in the composition of, and resource use by, soil microbial communities requires Eh predictability under shiftin ...

American Geophysical Union2023

Development of Hetero-Vinylbenziodoxolone Reagents for Applications in Synthetic Methodology and Biomolecule Functionalization

Nina Declas

Among the numerous existing chemical motifs, alkenes, alkynes, enol ethers and enamides, with an unsaturated carbon-carbon bond, are versatile functional groups that are found in many natural products and bioactive compounds. They are widely used as valuab ...

EPFL2023

Chronic warming and dry soils limit carbon uptake and growth despite a longer growing season in beech and oak

Charlotte Grossiord, Yann Vitasse, Margaux Clara Lou Didion-Gency

Progressively warmer and drier climatic conditions impact tree phenology and carbon cycling with large consequences for forest carbon balance. However, it remains unclear how individual impacts of warming and drier soils differ from their combined effects ...

Oxford Univ Press Inc2023

TiCl3-Mediated Reductive Cyclization of Tetrasubstituted Alkenes and Enol Esters Bearing a 2-Nitrophenyl Substituent

Dina Boyarskaya

Indole is one of the most important heterocycles widely present in bioactive natural products, pharmaceuticals, agrochemicals and materials. Being easily accessible, the 2-nitrostyrenes are attractive starting materials for the indole synthesis and the Cad ...

EPFL2023

Validation of GBS plasma turbulence simulation of the TJ-K stellarator

Paolo Ricci, Joaquim Loizu Cisquella

We present a validation of a three-dimensional, two-fluid simulation of plasma turbulence in the TJ-K stellarator, a low temperature plasma experiment ideally suited for turbulence measurements. The simulation is carried out by the GBS code, recently adapt ...

IOP Publishing Ltd2023

Addressing the challenges of homogeneity, quality control and waste handling in soil bio-cementation: A large-scale experiment

Lyesse Laloui, Dimitrios Terzis, Ray Harran

In an attempt to go beyond the conventional laboratory experiments widely reported in literature around the emerging technique of soil bio-cementation, this work addresses key challenges related to its large-scale application. Precisely, a state-of-the-art ...

JAPANESE GEOTECHNICAL SOC2023

Effect of a temperature gradient on the screening properties of ionic fluids

Andrea Grisafi, Federico Grasselli

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet the screening behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of thermoelectric p ...

AMER PHYSICAL SOC2023

Synthetic Receptors with Micromolar Affinity for Chloride in Water

Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Cesare Berton, Sylvain Alexandre Marie Sudan

A water-soluble coordination cage was obtained by reaction of Pd(NO3)2 with a 1,3-di(pyridin-3-yl)benzene ligand featuring a short PEG chain. The cavity of the metal-organic cage contains one nitrate anion, which is readily replaced by chloride. The appare ...

Wiley-VCH Verlag GmbH2023

CO2 Capture and Release in Amine Solutions: To What Extent Can Molecular Simulations Help Understand the Trends?

Wanda Andreoni, Fabio Pietrucci, Changru Ma

Absorption in amine solutions is a well-established advanced technology for CO2 capture. However, the fundamental aspects of the chemical reactions occurring in solution still appear to be unclear. Our previous investigation of aqueous monoethanolamine (ME ...

2023

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TiCl3-Mediated Reductive Cyclization of Tetrasubstituted Alkenes and Enol Esters Bearing a 2-Nitrophenyl Substituent

Dina Boyarskaya

EPFL2023

Addressing the challenges of homogeneity, quality control and waste handling in soil bio-cementation: A large-scale experiment

Lyesse Laloui, Dimitrios Terzis, Ray Harran

JAPANESE GEOTECHNICAL SOC2023

Synthetic Receptors with Micromolar Affinity for Chloride in Water

Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Cesare Berton, Sylvain Alexandre Marie Sudan

Wiley-VCH Verlag GmbH2023

Global Mapping of Potential and Climatic Plant‐Available Soil Water

Sara Bonetti, Dani Or

2023

Development of Hetero-Vinylbenziodoxolone Reagents for Applications in Synthetic Methodology and Biomolecule Functionalization

Nina Declas

EPFL2023