Publication

Sequential ATRA-Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese

Publications associées (32)

In depth analysis of heterogeneous catalysts for the chemoenzymatic dynamic kinetic resolution of beta-amino esters

Kumar Varoon Agrawal, Cédric Karel J Van Goethem

The chemoenzymatic dynamic kinetic resolution of beta-amino esters is established after detailed evaluation of metal-based heterogeneous catalysts for racemization and enzyme catalysts for kinetic resolution. Several heterogeneous palladium catalysts prove ...

ROYAL SOC CHEMISTRY2022

Ring-Opening Reactions of Aminocyclopropanes and Aminocyclobutanes

Mingming Wang

Nitrogen-containing compounds are an important class of molecules in medicinal chemistry, chemical biology, biochemistry, material sciences or environmental sciences. Organic nitrogen occurs in many forms, ranging from small building blocks such as urea, a ...

EPFL2022

Monitoring and understanding Cu catalyst dissolution during CO2 electroreduction

Jan Vávra

Electrochemical reduction of carbon dioxide is a promising approach to decrease the amount of anthropogenic CO2 being released into the atmosphere, provided that a surplus of renewable electrical energy is available. Copper based materials are at the cente ...

EPFL2022

Experimental and modeling-based analysis of reaction pathways on catalysts for natural gas engines under periodic lean/rich oscillations

Oliver Kröcher, Davide Ferri, Moyu Wang

Methane (CH4) has the prospective of becoming one of the major energy carriers for heavy-duty mobility, but its catalytic abatement remains a challenge. CH4 abatement reaction pathways were analyzed using targeted periodic lean/rich oscillations, which res ...

ELSEVIER SCIENCE SA2022

Emission reduction by targeted transient operations in three-way catalysts for heavy-duty natural gas applications

Moyu Wang

To curb the severe effects of climate change, our society needs to radically reduce its CO2 footprint. For the heavy-duty sector, where electrification is difficult, alternative fuels can be the solution. Methane-fueled engines have lower energy-specific C ...

EPFL2022

Development of Cyclopentadienylcobalt(III) Catalyzed Asymmetric C-H Functionalizations

Kristers Ozols

Transition metal catalyzed C-H activation plays a major role in modern organic chemistry, affording mild, selective and atom-efficient protocols. Most of current developments in the field rely on the use of several precious metals. As a consequence, an int ...

EPFL2022

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Christian Ludwig, Michel Rossi, Riccardo Iannarelli

Knudsen flow experiments and its interpretation in terms of adsorption/desorption kinetics as well as quantitative uptake on substrates of interest is presented together with the description of critical design parameters of the Knudsen Flow Reactor (KFR). ...

2022

Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Paul Varava

Examples for applications of nitrous oxide in organic synthesis remain rare up until today. First mayor contributions of our group were published in 2012, when nitrous oxide was successfully captured by N-heterocyclic carbenes. Subsequent studies investiga ...

EPFL2022

Molecular Volcano Plots: Tools for Rationalizing and Predicting the Performance of Homogeneous Catalysts

Boodsarin Sawatlon

The generation of catalyst design tools is important for developing both economically and environmentally friendly reactions. This thesis focuses on the use and development of such a tool, molecular volcano plots, which have the ability to estimate catalyt ...

EPFL2021

Sequential ATRA-Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese

In depth analysis of heterogeneous catalysts for the chemoenzymatic dynamic kinetic resolution of beta-amino esters

Ring-Opening Reactions of Aminocyclopropanes and Aminocyclobutanes

Monitoring and understanding Cu catalyst dissolution during CO2 electroreduction

Experimental and modeling-based analysis of reaction pathways on catalysts for natural gas engines under periodic lean/rich oscillations

Emission reduction by targeted transient operations in three-way catalysts for heavy-duty natural gas applications

Development of Cyclopentadienylcobalt(III) Catalyzed Asymmetric C-H Functionalizations

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Molecular Volcano Plots: Tools for Rationalizing and Predicting the Performance of Homogeneous Catalysts

Graph Chatbot

In depth analysis of heterogeneous catalysts for the chemoenzymatic dynamic kinetic resolution of beta-amino esters

Ring-Opening Reactions of Aminocyclopropanes and Aminocyclobutanes

Monitoring and understanding Cu catalyst dissolution during CO2 electroreduction

Experimental and modeling-based analysis of reaction pathways on catalysts for natural gas engines under periodic lean/rich oscillations

Emission reduction by targeted transient operations in three-way catalysts for heavy-duty natural gas applications

Development of Cyclopentadienylcobalt(III) Catalyzed Asymmetric C-H Functionalizations

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Hydro-processing of biomass using novel metal-organic framework (MOF)/polymer composite catalysts

Molecular Volcano Plots: Tools for Rationalizing and Predicting the Performance of Homogeneous Catalysts

Hydro-processing of biomass using novel metal-organic framework (MOF)/polymer composite catalysts