Catalytic Enantioselective Double Carbopalladation/C−H Functionalization with Statistical Amplification of Product Enantiopurity: A Convertible Linker Approach

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Regionalized Life Cycle Assessment of Food and Energy Systems

Xun Liao

To steer the sustainable transition in the food and energy sectors, reliable environmental data is required to answer environmental questions related to single agricultural crop, food product or energy technologies. Life cycle assessment (LCA) has been wid ...

EPFL2022

A Künneth theorem for configuration spaces

Kathryn Hess Bellwald

We construct a spectral sequence converging to the homology of the ordered configuration spaces of a product of parallelizable manifolds. To identify the second page of this spectral sequence, we introduce a version of the Boardman-Vogt tensor product for ...

2022

Laser-induced liquid micro-jets for drug delivery

Jan Krizek

Jet injection devices have been studied and developed for transdermal drug delivery to avoid the use of needles. Such contact-less devices provide several advantages such as better dose control, lateral and depth localisation, lower collateral damage than ...

EPFL2021

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Bastian Antoine Rodolphe Claude Muriel

Amino alcohols, cyclopropanes and nitriles are privileged structural motifs found in the scaffold of natural products and bioactive compounds. In addition, they are versatile building blocks in organic chemistry. The development of new and increasingly eff ...

EPFL2021

Cyber-Physical LPG Debutanizer Distillation Columns: Machine-Learning-Based Soft Sensors for Product Quality Monitoring

Jinzhi Lu

Refineries execute a series of interlinked processes, where the product of one unit serves as the input to another process. Potential failures within these processes affect the quality of the end products, operational efficiency, and revenue of the entire ...

2021

Automated Design: A Journey Across Modelling, Optimization, and Education

Cyril Picard

Machine intelligence greatly impacts almost all domains of our societies. It is profoundly changing the field of mechanical engineering with new technical possibilities and processes. The education of future engineers also needs to adapt in terms of techni ...

EPFL2021

Virtual metrology as an approach for product quality estimation in Industry 4.0: a systematic review and integrative conceptual framework

Dimitrios Kyritsis, Gökan May, Foivos Psarommatis Giannakopoulos

Virtual metrology (VM) involves estimating a product's quality directly from production process data without physically measuring it. This enables the product quality of each unit of production to be monitored in real time, while preserving the process eff ...

TAYLOR & FRANCIS LTD2022

Unconventional time-bandwidth performance of resonant cavities with nonreciprocal coupling

Camille Sophie Brès, Davide Grassani, Ivan Cardea, Kosmas Tsakmakidis

The time-bandwidth limit is a mathematical tenet that affects all reciprocal resonators, stating that the product of the spectral bandwidth that can couple into a resonant system and its characteristic energy decay time is always equal to 1. Here, we devel ...

2021

New Vinylation and Alkynylation Strategies with Hypervalent Iodine Reagents and Diazo Compounds

Guillaume Dominique Pisella

The development of a sequential copper-catalyzed oxy-alkynylation/intramolecular [4+2] cycloaddition of allenes and arenes was investigated at first. This one-pot protocol allowed the construction of complex polycylic architectures with high efficiency fro ...

EPFL2021

Visible-Light-Driven Catalytic Deracemization of Secondary Alcohols

Xile Hu, Zhikun Zhang

Deracemization of racemic chiral compounds is an attractive approach in asymmetric synthesis, but its development has been hindered by energetic and kinetic challenges. Here we describe a catalytic deracemization method for secondary benzylic alcohols whic ...

Wiley-VCH Verlag GmbH2021

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Virtual metrology as an approach for product quality estimation in Industry 4.0: a systematic review and integrative conceptual framework

Dimitrios Kyritsis, Gökan May, Foivos Psarommatis Giannakopoulos

TAYLOR & FRANCIS LTD2022