Enantioselective Access to Spirocyclic Sultams by Chiral Cp-x-Rhodium(III)-Catalyzed Annulations

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Development of New Strategies of Umpolung with Cyclic Hypervalent Iodine Reagents

Paola Caramenti

Organic chemistry is essential for the development of a modern society and technical progress requires the continuous development of synthetic methodologies Novel, efficient, selective and flexible protocols are employed to access complex frameworks from s ...

EPFL2019

A Precious Catalyst: Rhodium-Catalyzed Formic Acid Dehydrogenation in Water

Gabor Laurenczy, Cornel Fink

The performance of rhodium complex [Cp*Rh(bis(pyrazol-1-yl)methane)Cl]Cl was evaluated for formic acid dehydrogenation in aqueous solution. Solid-state X-ray diffraction helped to confirm the catalyst structure. Multinuclear NMR spectroscopy was employed t ...

WILEY-V C H VERLAG GMBH2019

C-Terminal Bioconjugation of Peptides through Photoredox Catalyzed Decarboxylative Alkynylation

Jérôme Waser, Franck Le Vaillant, Marion Marie-Agnès Garreau

We report the first decarboxylative alkynylation of the C-terminus of peptides starting from free carboxylic acids. The reaction is fast, metal-free, and proceeds cleanly to afford alkynylated peptides with a broad tolerance for the C-terminal amino acid. ...

Wiley-VCH Verlag GmbH2019

Enantioselective Synthesis of Chiral-at-Sulfur 1,2-Benzothiazines by (CpRhIII)-Rh-x-Catalyzed C-H Functionalization of Sulfoximines

Nicolai Cramer, Yang Sun

Sulfoximines with stereogenic sulfur atoms are attractive structural motifs in drug discovery. A direct catalytic enantioselective method for the synthesis of sulfur-chiral 1,2-benzothiazines from readily accessible diaryl sulfoximines is presented. Rhodiu ...

Wiley-VCH Verlag GmbH2018

Scanning Probe Microscopy Characterization of Organic Self-Assembled Monolayers

Evangelia-Nefeli Athanasopoulou

As technology advances, surface coatings become more and more important to assure materials performances. In recent years, molecular coatings have found larger acceptance and uses. Among them, self-assembled monolayers (SAMs) are attractive because they ar ...

EPFL2018

Splines Are Universal Solutions of Linear Inverse Problems with Generalized TV Regularization

Michaël Unser, Julien René Pierre Fageot, John Paul Ward

Splines come in a variety of flavors that can be characterized in terms of some differential operator L. The simplest piecewise-constant model corresponds to the derivative operator. Likewise, one can extend the traditional notion of total variation by con ...

2017

Combinatorial presentation of multidimensional persistent homology

Martina Scolamiero

A multifiltration is a functor indexed by Nr that maps any morphism to a monomorphism. The goal of this paper is to describe in an explicit and combinatorial way the natural Nr-graded R[x(1),...x(r)]-module structure on the homology of a multifiltration of ...

Elsevier2017

On finitely generated modules over quasi-Euclidean rings

Luc Guyot

Let R be a unital commutative ring, and let M be an R-module that is generated by k elements but not less. Let be the subgroup of generated by the elementary matrices. In this paper we study the action of by matrix multiplication on the set of unimodular r ...

Springer Verlag2017

A Discontinuous Galerkin Reduced Basis Element Method For Elliptic Problems

Alfio Quarteroni, Paolo Pacciarini

We propose and analyse a new discontinuous reduced basis element method for the approximation of parametrized elliptic PDEs in partitioned domains. The method is built upon an offline stage (parameter independent) and an online (parameter dependent) one. I ...

Edp Sciences S A2016

Rh(III)-Catalyzed C-H Functionalizations as Strategies for Versatile Organic Building Blocks

Van Manh Pham

Transition-metal catalyzed C-H functionalizations have impacted and changed synthetic approaches towards the construction of relevant complex molecules, comprising natural products, active pharmaceutical ingredients, and organic materials. This thesis desc ...

EPFL2016