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This lecture covers the application of geochemical modeling in understanding environmental systems. Topics include the use of the Geochemist's Workbench, selenium speciation in groundwater, creating stability diagrams, estimating the growth of the Dreimühlen waterfall, and equilibrium equations. Practical exercises involve creating E-pH diagrams, exporting plots, and calculating the precipitation of minerals. The lecture also delves into redox disequilibrium scenarios and the chemical processes behind the formation of calcite in the Dreimühlen waterfall.