Anionic Polymerization: Mechanisms and Applications

This lecture by the instructor covers the concept of anionic polymerization, focusing on the differences between anionic and cationic polymerization. It explains the initiation process using nucleophilic initiators and electron transfer. The lecture delves into the living and controlled polymerization, emphasizing the importance of fast initiation and exchange among propagating species. Practical aspects of anionic polymerization, such as high vacuum conditions and macromolecular engineering, are also discussed. The lecture concludes with a detailed explanation of the kinetics of living anionic polymerization and the factors affecting the reaction medium.