This lecture covers the principles of radiative transfer in participating media, focusing on the interactions of radiation with matter. The instructor begins by outlining the course structure and the transition from previous topics to the new focus on radiation and participating media. Key concepts such as the radiative transfer equation (RTE) are introduced, emphasizing the importance of understanding how radiation interacts with media that absorb and scatter light. The lecture explains the phenomena of attenuation due to absorption and scattering, detailing how these processes affect the intensity of radiation as it travels through a medium. The instructor discusses the extinction coefficient, its dependence on various factors, and how it relates to Beer-Lambert's law. The lecture also explores the significance of the scattering phase function and its role in determining the behavior of radiation in different media. Finally, the connection between the radiative transfer equation and energy conservation is established, providing a comprehensive understanding of how radiation contributes to heat transfer in participating media.