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Metallica: A large contraction of the PtPt bond in the triplet excited state of the photoreactive [Pt2(P2O5H2)4]4- ion is determined by time-resolved X-ray absorption spectroscopy (see picture). The strengthening of the PtPt interaction is accompanied by a weakening of the ligand coordination bonds, resulting in an elongation of the platinum-ligand bond that is determined for the first time.
Kay Severin, Farzaneh Fadaei Tirani, Noga Eren
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Bastiaan Kooij, Zhaowen Dong
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Laura Piveteau, Bastiaan Kooij, Zhaowen Dong, Paul Varava