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An unsymmetrical, push-pull porphyrazine derivative bearing an isoindole-4-carboxylic acid moiety (TT112) is synthesized and incorporated in a dye-sensitized solar cell (DSSC). The device, which constitutes the first example of a porphyrazine-sensitized solar cell, exhibits a maximum power conversion efficiency of 3.4 %.
Michael Graetzel, Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Etienne Christophe Socie, Weiwei Zhang, Brian Irving Carlsen, Yinghui Wu, Yameng Ren, Huiyun Jiang
Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Kazuteru Nonomura, Gunther Wittstock