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Publication
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Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
We have identified a polydentate aminocarboxylate ligand that stabilizes uranyl(V) in water. The mononuclear [UO2(dpaea)]X, (dpaeaH2 = Bis(pyridyl-6-methyl-2-carboxylate)-ethylamine; X = CoCp2*+ or X = K(2.2.2.cryptand) complexes have been isolated from anaerobic organic solution, crystallographically and spectroscopically characterized both in water and organic solution. These complexes disproportionate at pH ≤ 6, but are stable in anaerobic water at pH 7–10 for several days.
César Pulgarin, Michaël Bensimon, Stefanos Giannakis, Thomas Guillaume, Jérémie Decker
Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Cesare Berton, Sylvain Alexandre Marie Sudan
Jérôme Waser, Durga Prasada Rao Hari, Romain Gaëtan Tessier, Abhaya Kumar Mishra