Publication

Processing and micro-mechanical characterization of multi-component transition MC carbides in iron

Abstract

We prepare multi-component transition monocarbides of chosen composition by arc-melting together a pre-alloy of the transition metals and cast iron. Based on the elements Ti, Ta, V, Nb and W, 51 different binary, ternary and quaternary compositions are produced. The intrinsic hardness H and modulus E of the resulting iron-embedded carbide particles are directly measured using nanoindentation. Of all compositions tested here WC shows the highest modulus while two (Ta,V)C and (Ti,W)C carbides are shown to have a hardness 15% higher than that of all binary carbides; some (Ti,Ta,V)C compositions furthermore display interesting combinations of properties. The modulus and hardness variations with composition show that the valence electron concentration, which has been proposed to be a dominant parameter in predicting carbide hardness and modulus, is not a useful single predictor of optimal compositions. Other important parameters therefore also govern the hardness and modulus of MC carbides.

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Related concepts (37)
Cast iron
Cast iron is a class of iron–carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured; white cast iron has carbide impurities which allow cracks to pass straight through, grey cast iron has graphite flakes which deflect a passing crack and initiate countless new cracks as the material breaks, and ductile cast iron has spherical graphite "nodules" which stop the crack from further progressing.
Iron
Iron is a chemical element with the symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, just ahead of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust, being mainly deposited by meteorites in its metallic state, with its ores also being found there.
Ductile iron
Ductile iron, also known as ductile cast iron, nodular cast iron, spheroidal graphite iron, spheroidal graphite cast iron and SG iron, is a type of graphite-rich cast iron discovered in 1943 by Keith Millis. While most varieties of cast iron are weak in tension and brittle, ductile iron has much more impact and fatigue resistance, due to its nodular graphite inclusions. On October 25, 1949, Keith Dwight Millis, Albert Paul Gagnebin and Norman Boden Pilling received US patent 2,485,760 on a cast ferrous alloy for ductile iron production via magnesium treatment.
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