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Publication
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The preparation and the structural characterization of vanadium complexes with terminal and bridging N-heterocyclic vinylidene ligands is reported. The synthesis of the complexes was enabled by utilization of diazoolefins as ligand precursors. Structural data and theoretical results show that N-heterocyclic vinylidenes can act as 6e− donor ligands, leading to strong metal–carbon interactions.
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Bastiaan Kooij, Zhaowen Dong
Pierre Vogel, Florence Pojer, George Coukos, Somi Reddy Majjigapu, Olivier Michielin
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Paul Varava, Wolfram Feuerstein