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The hydrogenation of benzene and other arenes under aqueous-organic biphasic conditions is evaluated using the ruthenium complexes Ru(eta(6)-C10H14)(pta)Cl-2 (pta=1,3,5-triaza-7-phosphaadamantane), Ru(eta(6)-C10H14)(tppts)Cl-2 (tppts=tris-3-sulfonatophenylphosphine trisodium salt) and Ru(eta(6)-C10H14)(pta)(2)Cl. The active catalysts formed during the hydrogenations correspond to a trinuclear cluster, a colloid and a mononuclear complex, respectively.
Paul Joseph Dyson, Farzaneh Fadaei Tirani, Mouna Hadiji
Moreno Lelli, Pierrick Berruyer, David Benjamin Roger Antoine Gajan, Zhuoran Wang
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Andrzej Sienkiewicz, Abdusalom Suleymanov, Zhaowen Dong, Cesare Berton