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Concept
Hydroxide
Summary
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical.
The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group.
Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.
Many inorganic substances which bear the word hydroxide in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.
The hydroxide ion is naturally produced from water by the self-ionization reaction:
H3O+ + OH− 2H2O
The equilibrium constant for this reaction, defined as
Kw = [H+][OH−]
has a value close to 10−14 at 25 °C, so the concentration of hydroxide ions in pure water is close to 10−7 mol∙dm−3, in order to satisfy the equal charge constraint. The pH of a solution is equal to the decimal cologarithm of the hydrogen cation concentration; the pH of pure water is close to 7 at ambient temperatures. The concentration of hydroxide ions can be expressed in terms of pOH, which is close to (14 − pH), so the pOH of pure water is also close to 7. Addition of a base to water will reduce the hydrogen cation concentration and therefore increase the hydroxide ion concentration (increase pH, decrease pOH) even if the base does not itself contain hydroxide. For example, ammonia solutions have a pH greater than 7 due to the reaction NH3 + H+ NH4+, which decreases the hydrogen cation concentration, which increases the hydroxide ion concentration. pOH can be kept at a nearly constant value with various buffer solutions.
Official source
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