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Concept
Carbonate rock
Summary
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). They are usually classified based on texture and grain size. Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed, marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava.
Carbonate rocks are also crucial components to understanding geologic history due to processes such as diagenesis in which carbonates undergo compositional changes based on kinetic effects. The correlation between this compositional change and temperature can be exploited to reconstruct past climate as is done in paleoclimatology. Carbonate rocks can also be used for understanding various other systems as described below.
Limestone is the most common carbonate rock and is a sedimentary rock made of calcium carbonate with two main polymorphs: calcite and aragonite. While the chemical composition of these two minerals is the same, their physical properties differ significantly due to their different crystalline form. The most common form found in the seafloor is calcite, while aragonite is more found in biological organisms.
Calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature, pH, and dissolved ion concentrations. Calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases. When conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together or it can fill fractures.
Compared to calcite, aragonite is less stable and more soluble, and can thus be converted to calcite under certain conditions.
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