In nuclear astrophysics, the rapid neutron-capture process, also known as the r-process, is a set of nuclear reactions that is responsible for the creation of approximately half of the atomic nuclei heavier than iron, the "heavy elements", with the other half produced by the p-process and s-process. The r-process usually synthesizes the most neutron-rich stable isotopes of each heavy element. The r-process can typically synthesize the heaviest four isotopes of every heavy element, and the two heaviest isotopes, which are referred to as r-only nuclei, can be created via the r-process only. Abundance peaks for the r-process occur near mass numbers A = 82 (elements Se, Br, and Kr), A = 130 (elements Te, I, and Xe) and A = 196 (elements Os, Ir, and Pt).
The r-process entails a succession of rapid neutron captures (hence the name) by one or more heavy seed nuclei, typically beginning with nuclei in the abundance peak centered on 56Fe. The captures must be rapid in the sense that the nuclei must not have time to undergo radioactive decay (typically via β− decay) before another neutron arrives to be captured. This sequence can continue up to the limit of stability of the increasingly neutron-rich nuclei (the neutron drip line) to physically retain neutrons as governed by the short range nuclear force. The r-process therefore must occur in locations where there exists a high density of free neutrons. Early studies theorized that 1024 free neutrons per cm3 would be required, for temperatures about 1 GK, in order to match the waiting points, at which no more neutrons can be captured, with the mass numbers of the abundance peaks for r-process nuclei. This amounts to almost a gram of free neutrons in every cubic centimeter, an astonishing number requiring extreme locations. Traditionally this suggested the material ejected from the reexpanded core of a core-collapse supernova, as part of supernova nucleosynthesis, or decompression of neutron-star matter thrown off by a binary neutron star merger in a kilonova.