Vulcanization (British: Vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to include the hardening of other (synthetic) rubbers via various means. Examples include silicone rubber via room temperature vulcanizing and chloroprene rubber (neoprene) using metal oxides.
Vulcanization can be defined as the curing of elastomers, with the terms 'vulcanization' and 'curing' sometimes used interchangeably in this context. It works by forming cross-links between sections of polymer chain which results in increased rigidity and durability, as well as other changes in the mechanical and electrical properties of the material. Vulcanization, in common with the curing of other thermosetting polymers, is generally irreversible.
The word was suggested by William Brockedon (a friend of Thomas Hancock who attained the British patent for the process) coming from the god Vulcan who was associated with heat and sulfur in volcanoes.
Rubber – latex – had been known for thousands of years in Mesoamerican cultures, used to make balls, sandal soles, rubber bands, and waterproof containers. Rubber was processed for specific applications within the Aztec Empire – rubber and latex goods were processed and constructed, and then shipped to the capital for use or further distribution.
Early rubber tube tires in the 19th century would grow sticky on a hot road. Debris would get stuck in them and eventually the tires would burst.
Charles Goodyear, in the 1830s, was working to improve those tube tires. He tried heating up rubber in order to mix other chemicals with it. This seemed to harden and improve the rubber, though this was due to the heating itself and not the chemicals used. Not realizing this, he repeatedly ran into setbacks when his announced hardening formulas did not work consistently. One day in 1839, when trying to mix rubber with sulfur, Goodyear accidentally dropped the mixture in a hot frying pan.
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The student has a basic understanding of the physical and physicochemical principles which result from the chainlike structure of synthetic macromolecules. The student can predict major characteristic
The first part of the course is devoted to the self-assembly of molecules. In the second part we discuss basic physical chemical principles of polymers in solutions, at interfaces, and in bulk. Finall
Explores the flow behavior, models, viscosity, processing, and elastic properties of polymers, including thermoplasts, thermosets, elastomers, and 3D printing.
In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural polymers (such as proteins). In polymer chemistry "cross-linking" usually refers to the use of cross-links to promote a change in the polymers' physical properties. When "crosslinking" is used in the biological field, it refers to the use of a probe to link proteins together to check for protein–protein interactions, as well as other creative cross-linking methodologies.
Rubber, also called India rubber, latex, Amazonian rubber, caucho, or caoutchouc, as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, Indonesia, and Cambodia are four of the leading rubber producers. Types of polyisoprene that are used as natural rubbers are classified as elastomers. Currently, rubber is harvested mainly in the form of the latex from the rubber tree (Hevea brasiliensis) or others.
An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus (E) and high failure strain compared with other materials. The term, a portmanteau of elastic polymer, is often used interchangeably with rubber, although the latter is preferred when referring to vulcanisates. Each of the monomers which link to form the polymer is usually a compound of several elements among carbon, hydrogen, oxygen and silicon.
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