In physics, quintessence is a hypothetical form of dark energy, more precisely a scalar field, postulated as an explanation of the observation of an accelerating rate of expansion of the universe. The first example of this scenario was proposed by Ratra and Peebles (1988) and Wetterich (1988). The concept was expanded to more general types of time-varying dark energy, and the term "quintessence" was first introduced in a 1998 paper by Robert R. Caldwell, Rahul Dave and Paul Steinhardt. It has been proposed by some physicists to be a fifth fundamental force. Quintessence differs from the cosmological constant explanation of dark energy in that it is dynamic; that is, it changes over time, unlike the cosmological constant which, by definition, does not change. Quintessence can be either attractive or repulsive depending on the ratio of its kinetic and potential energy. Those working with this postulate believe that quintessence became repulsive about ten billion years ago, about 3.5 billion years after the Big Bang. A group of researchers argued in 2021 that observations of the Hubble tension may imply that only quintessence models with a nonzero coupling constant are viable. The name comes from quinta essentia (fifth element). So called in Latin starting from the Middle Ages, this was the (first) element added by Aristotle to the other four ancient classical elements because he thought it was the essence of the celestial world. Aristotle posited to be a pure, fine, and primigenial element. Later scholars identified this element with aether. Similarly, modern quintessence would be the fifth known "dynamical, time-dependent, and spatially inhomogeneous" contribution to the overall mass–energy content of the universe. Of course, the other four components are not the ancient Greek classical elements, but rather "baryons, neutrinos, dark matter, [and] radiation." Although neutrinos are sometimes considered radiation, the term "radiation" in this context is only used to refer to massless photons.

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