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Concept
Mineral hydration
Summary
In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.
In geological terms, the process of mineral hydration is known as retrograde alteration and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity.
There are two main ways in which minerals hydrate. One is conversion of an oxide to a double hydroxide, as with the hydration of calcium oxide—CaO—to calcium hydroxide—Ca(OH)2, the other is with the incorporation of water molecules directly into the crystalline structure of a new mineral.
The later process is exhibited in the hydration of feldspars to clay minerals, garnet to chlorite, or kyanite to muscovite.
Mineral hydration is also a process in the regolith that results in conversion of silicate minerals into clay minerals.
Some mineral structures, for example, montmorillonite, are capable of including a variable amount of water without significant change to the mineral structure.
Hydration is the mechanism by which hydraulic binders such as Portland cement develop strength. A hydraulic binder is a material that can set and harden submerged in water by forming insoluble products in a hydration reaction. The term hydraulicity or hydraulic activity is indicative of the chemical affinity of the hydration reaction.
Examples of hydrated minerals include:
silicates (SiO44-, SiO2)
phyllosilicates, clay minerals "commonly found on Earth as weathering products of rocks or in hydrothermal systems"
chlorite
muscovite
non-silicates
oxides (O2-, Al2O3, Fe2O3, etc.) and oxy-hydroxides
brucite,
goethite, FeO(OH)
carbonates (CO32-, etc.)
hydromagnesite,
ikaite, , the unstable hexahydrate form of calcium carbonate
hydroxylated minerals
saponite
talc
hydroxysulfides (mixed sulfides-hydr
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