Ozone–oxygen cycle

The ozone–oxygen cycle is the process by which ozone is continually regenerated in Earth's stratosphere, converting ultraviolet radiation (UV) into heat. In 1930 Sydney Chapman resolved the chemistry involved. The process is commonly called the Chapman cycle by atmospheric scientists. Most of the ozone production occurs in the tropical upper stratosphere and mesosphere. The total mass of ozone produced per day over the globe is about 400 million metric tons. The global mass of ozone is relatively constant at about 3 billion metric tons, meaning the Sun produces about 12% of the ozone layer each day. The Chapman cycle describes the main reactions that naturally determine, to first approximation, the concentration of ozone in the stratosphere. It includes four processes, and a fifth, less important one, all involving oxygen atoms and molecules, as well as UV radiation: An oxygen molecule is split (photolyzed) by higher frequency UV light (top end of UV-B, UV-C and above) into two oxygen atoms (see figure):

1. oxygen photodissociation: O2 + hν(