Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word σίδηρος (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly substitute for the iron, resulting in the siderite-smithsonite, siderite-magnesite, and siderite-rhodochrosite solid solution series.
Siderite has Mohs hardness of 3.75 to 4.25, a specific gravity of 3.96, a white streak and a vitreous lustre or pearly luster. Siderite is antiferromagnetic below its Néel temperature of which can assist in its identification.
It crystallizes in the trigonal crystal system, and are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese.
Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It is also a common diagenetic mineral in shales and sandstones, where it sometimes forms concretions, which can encase three-dimensionally preserved fossils. In sedimentary rocks, siderite commonly forms at shallow burial depths and its elemental composition is often related to the depositional environment of the enclosing sediments. In addition, a number of recent studies have used the oxygen isotopic composition of sphaerosiderite (a type associated with soils) as a proxy for the isotopic composition of meteoric water shortly after deposition.
Although carbonate iron ores, such as siderite, have been economically important for steel production, they are far from ideal as an ore.
Their hydrothermal mineralisation tends to form them as small ore lenses, often following steeply dipping bedding planes. This makes them not amenable to opencast working, and increases the cost of working them by mining with horizontal stopes. As the individual ore bodies are small, it may also be necessary to duplicate or relocate the pit head machinery, winding engine and pumping engine, between these bodies as each is worked out.