Molecular sieveA molecular sieve is a material with pores (very small holes) of uniform size. These pore diameters are similar in size to small molecules, and thus large molecules cannot enter or be adsorbed, while smaller molecules can. As a mixture of molecules migrates through the stationary bed of porous, semi-solid substance referred to as a sieve (or matrix), the components of the highest molecular weight (which are unable to pass into the molecular pores) leave the bed first, followed by successively smaller molecules.
Critical fieldFor a given temperature, the critical field refers to the maximum magnetic field strength below which a material remains superconducting. Superconductivity is characterized both by perfect conductivity (zero resistance) and by the complete expulsion of magnetic fields (the Meissner effect). Changes in either temperature or magnetic flux density can cause the phase transition between normal and superconducting states. The highest temperature under which the superconducting state is seen is known as the critical temperature.
PerovskitePerovskite (pronunciation: pə'rɒvskaɪt) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as the perovskite structure. Many different cations can be embedded in this structure, allowing the development of diverse engineered materials. The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856).
Single-molecule magnetA single-molecule magnet (SMM) is a metal-organic compound that has superparamagnetic behavior below a certain blocking temperature at the molecular scale. In this temperature range, a SMM exhibits magnetic hysteresis of purely molecular origin. In contrast to conventional bulk magnets and molecule-based magnets, collective long-range magnetic ordering of magnetic moments is not necessary. Although the term "single-molecule magnet" was first employed in 1996, the first single-molecule magnet, [Mn12O12(OAc)16(H2O)4] (nicknamed "Mn12") was reported in 1991.
CrystallinityCrystallinity refers to the degree of structural order in a solid. In a crystal, the atoms or molecules are arranged in a regular, periodic manner. The degree of crystallinity has a big influence on hardness, density, transparency and diffusion. In an ideal gas, the relative positions of the atoms or molecules are completely random. Amorphous materials, such as liquids and glasses, represent an intermediate case, having order over short distances (a few atomic or molecular spacings) but not over longer distances.
Supercritical dryingSupercritical drying, also known as critical point drying, is a process to remove liquid in a precise and controlled way. It is useful in the production of microelectromechanical systems (MEMS), the drying of spices, the production of aerogel, the decaffeination of coffee and in the preparation of biological specimens. As the substance in a liquid body crosses the boundary from liquid to gas (see green arrow in phase diagram), the liquid changes into gas at a finite rate, while the amount of liquid decreases.
Air separationAn air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases. The most common method for air separation is fractional distillation. Cryogenic air separation units (ASUs) are built to provide nitrogen or oxygen and often co-produce argon. Other methods such as membrane, pressure swing adsorption (PSA) and vacuum pressure swing adsorption (VPSA) are commercially used to separate a single component from ordinary air.
Barkhausen effectThe Barkhausen effect is a name given to the noise in the magnetic output of a ferromagnet when the magnetizing force applied to it is changed. Discovered by German physicist Heinrich Barkhausen in 1919, it is caused by rapid changes of size of magnetic domains (similarly magnetically oriented atoms in ferromagnetic materials). Barkhausen's work in acoustics and magnetism led to the discovery, which became the main piece of experimental evidence supporting the domain theory of ferromagnetism proposed in 1906 by Pierre-Ernest Weiss.
Magnetic energyMagnetic energy and electrostatic potential energy are related by Maxwell's equations. The potential energy of a magnet or magnetic moment in a magnetic field is defined as the mechanical work of the magnetic force (actually magnetic torque) on the re-alignment of the vector of the magnetic dipole moment and is equal to: while the energy stored in an inductor (of inductance ) when a current flows through it is given by: This second expression forms the basis for superconducting magnetic energy storage.
Persistent currentIn physics, persistent current refers to a perpetual electric current, not requiring an external power source. Such a current is impossible in normal electrical devices, since all commonly-used conductors have a non-zero resistance, and this resistance would rapidly dissipate any such current as heat. However, in superconductors and some mesoscopic devices, persistent currents are possible and observed due to quantum effects. In resistive materials, persistent currents can appear in microscopic samples due to size effects.
