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Several hydrophobic long-chain quaternary ammonium and phosphonium ionic liquids (ILs) with functionalized aromatic anions were prepared following a metathesis route using tricaprylmethylammonium chloride (Aliquat 336) and trihexyl(tetradecyl) phosphonium ...
The utility of molten salts was demonstrated in the synthesis of the 1st family of mesoporous salt-inclusion solids featuring [V4O16] and [V5O17] polyoxovanadate (POV) units interlinked by As5+ cations, Cs3.5Na1.47(V5O9)(AsO4)2Cl2.33, Cs3.88Na0.12(V4.6O8.6 ...
Selective Laser Sintering (SLS) and Selective Laser Melting (SLM) are parent Additive Manufacturing processes using a laser to solidify metallic, ceramic, polymer or composite powders. During the process, the object is built layer by layer. A laser source ...
The anal. of potential energy surfaces of ion pairs within the framework of an anharmonic oscillator model allows rationalization and prediction of m.ps. (Tmp) and heat capacities (Cp) of ionic liqs. (ILs) comprising di- and trialkylimidazolium or tetraalk ...
Amidst a backdrop of rapidly increasing world-wide electricity demand, solar thermal power generation shows great potential for supplying the electricity needs of numerous countries in the Sun-belt regions of the world. In these regions, the absence of sig ...
Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd-0 nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd-0/SILP/ACF). The results were markedly differe ...
The present book is the result of more than half a century of teaching and research in thermodynamics at the Swiss Federal Institute of Technology (Ecole Polytechnique Fédérale of Lausanne), known as the EPFL, in Switzerland. Its objective is to facilitate ...
Presses Polytechniques et Universitaires Romandes PPUR2010
One of the primary tasks of Pumped Storage Power Plants (PSPP) in this era of rapidly growing renewable energy sources like wind and solar energy is to provide for energy storage while contributing to the stabilization of the electrical grid. Fast reaction ...
We present a comparison between spectrally-resolved reflection measurements of gratings and theoretical predictions from RCWA approach. Diffraction intensities vary significantly with polarization, and surface plasmon absorption is observed around the onse ...
A large series of ionic liqs. (ILs) based on the weakly coordinating alkoxyaluminate [Al(hfip)4]- (hfip: hexafluoroisopropoxy) with classical as well as functionalized cations were prepd., and their principal phys. properties detd. M.ps. are between 0 ([C4 ...