Self-cleaning surfacesSelf-cleaning surfaces are a class of materials with the inherent ability to remove any debris or bacteria from their surfaces in a variety of ways. The self-cleaning functionality of these surfaces are commonly inspired by natural phenomena observed in lotus leaves, gecko feet, and water striders to name a few. The majority of self-cleaning surfaces can be placed into three categories: superhydrophobic superhydrophilic photocatalytic. The first instance of a self-cleaning surface was created in 1995. Paz et al.
Surface reconstructionSurface reconstruction refers to the process by which atoms at the surface of a crystal assume a different structure than that of the bulk. Surface reconstructions are important in that they help in the understanding of surface chemistry for various materials, especially in the case where another material is adsorbed onto the surface. In an ideal infinite crystal, the equilibrium position of each individual atom is determined by the forces exerted by all the other atoms in the crystal, resulting in a periodic structure.
Quantum phase transitionIn physics, a quantum phase transition (QPT) is a phase transition between different quantum phases (phases of matter at zero temperature). Contrary to classical phase transitions, quantum phase transitions can only be accessed by varying a physical parameter—such as magnetic field or pressure—at absolute zero temperature. The transition describes an abrupt change in the ground state of a many-body system due to its quantum fluctuations. Such a quantum phase transition can be a second-order phase transition.
ChemisorptionChemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion, and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different phases. The strong interaction between the adsorbate and the substrate surface creates new types of electronic bonds.
PhysisorptionPhysisorption, also called physical adsorption, is a process in which the electronic structure of the atom or molecule is barely perturbed upon adsorption. The fundamental interacting force of physisorption is Van der Waals force. Even though the interaction energy is very weak (~10–100 meV), physisorption plays an important role in nature. For instance, the van der Waals attraction between surfaces and foot-hairs of geckos (see Synthetic setae) provides the remarkable ability to climb up vertical walls.
Angle-resolved photoemission spectroscopyAngle-resolved photoemission spectroscopy (ARPES) is an experimental technique used in condensed matter physics to probe the allowed energies and momenta of the electrons in a material, usually a crystalline solid. It is based on the photoelectric effect, in which an incoming photon of sufficient energy ejects an electron from the surface of a material. By directly measuring the kinetic energy and emission angle distributions of the emitted photoelectrons, the technique can map the electronic band structure and Fermi surfaces.
Specific surface areaSpecific surface area (SSA) is a property of solids defined as the total surface area of a material per unit of mass, (with units of m2/kg or m2/g) or solid or bulk volume (units of m2/m3 or m−1). It is a physical value that can be used to determine the type and properties of a material (e.g. soil or snow). It has a particular importance for adsorption, heterogeneous catalysis, and reactions on surfaces. Values obtained for specific surface area depend on the method of measurement.
GoniometerA goniometer is an instrument that either measures an angle or allows an object to be rotated to a precise angular position. The term goniometry derives from two Greek words, γωνία (gōnía) 'angle' and μέτρον (métron) 'measure'. The protractor is a commonly-used type in the fields of mechanics, engineering and geometry. The first known description of a goniometer, based on the astrolabe, was by Gemma Frisius in 1538. A protractor is a measuring instrument, typically made of transparent plastic or glass, for measuring angles.
Young–Laplace equationIn physics, the Young–Laplace equation (ləˈplɑːs) is an algebraic equation that describes the capillary pressure difference sustained across the interface between two static fluids, such as water and air, due to the phenomenon of surface tension or wall tension, although use of the latter is only applicable if assuming that the wall is very thin. The Young–Laplace equation relates the pressure difference to the shape of the surface or wall and it is fundamentally important in the study of static capillary surfaces.
GrapheneGraphene (ˈgræfiːn) is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure. The name is derived from "graphite" and the suffix -ene, reflecting the fact that the graphite allotrope of carbon contains numerous double bonds. Each atom in a graphene sheet is connected to its three nearest neighbors by σ-bonds and a delocalised π-bond, which contributes to a valence band that extends over the whole sheet.
