Concept

Hexane

Related publications (27)

Perhydrocarbyl Re-VII complexes: Comparison of molecular and surface complexes

The molecular complex [Re(equivalent toC(t)Bu)(=(CHBu)-Bu-t)((CH2Bu)-Bu-t)2] (1) reacts with a silica partially dehydroxylated at 700 degreesC to give syn-2, [(equivalent toSiO)Re(equivalent toC(t)Bu)(=(CHBu)-Bu-t)((CH2Bu)-Bu-t)], as a single isomer accord ...

AMER CHEMICAL SOC2003

Catalytic hydrogenation by triruthenium clusters: A mechanistic study with parahydrogen-induced polarization

Paul Joseph Dyson

The reactivity of the cluster family [Ru-3(CO)(12-x)(L)x] (in which L = PMe3, PMe2Ph, PPh3 and PCy3, x = 1 - 3) towards hydrogen is described. When x=2, three isomers of [Ru-3(H)(mu-H)(CO)(9)(L)(2)] are formed, which differ in the arrangement of their equa ...

2003

Partial oxidation of benzene catalyzed by heteropoly compounds

Albert Renken, Igor Iouranov, Benoît Louis

V substituted phosphomolybdic acids could hydroxylate benzene with nearly 100% selectivity at appreciable conversion levels in the presence of oxidizing agents like H2O2 and AcOOH. There appears to be a correlation, for the liq. phase, between phenol yield ...

2001

Gravimetric analysis of organic contamination in railway ballast

David Andrew Barry

Railway ballast provides both the foundation and drainage for railway track. It can become heavily contaminated with diesel fuel due to leakage and spillage. Typical analytical methods for soils may not be applicable to the assessment of ballast. The effic ...

2000

Isopulegol as a model compound. Metalation and substitution of an allylic position in the presence of an unprotected hydroxy function

When treated with BuLi and KOCMe3 for 2 h at 0 Deg in hexane, the unsatd. monoterpenic alc. isopulegol is simultaneously deprotonated at the hydroxy function and the allylic Me group. The metaloxy allylmetal species thus generated can be silylated, alkylat ...

1999

Functionalisation of gold surfaces via topological templates

Horst Vogel, Claus Duschl, Dimitrios Stamou

Regioselectivity addressable functionalised templates (RAFT) represent topological cyclic peptides containing orthogonally protected attachment sites pointing to opposite faces of the template backbone. Functionalisation of the template with coordinating g ...

1998

Ring tension, hydrocarbon acidity, and new super-bases

Addn. of di-Na pinacolate or KOCMe3 increased the transmetalating power of pentylsodium in alkane solvents. Some hydrocarbons thus metalated were Me3CCH:CH2, camphene, bicyclo[2.2.2]octene, spiro[4.4]nona-1,3-diene, nortricyclane, norcarane, and housane. C ...

1986

Graph Chatbot

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.