Concept

Spin trapping

Related publications (37)

Innovation as Paradigm : the CAF, 15th Arrondissement, Paris (1953-2008)

Raymond Lopez and Michel Holley's superlative scheme for the Caisse Centrale d’Allocations Familiales de la Région Parisienne (CCAFRP, shortened to CAF) was the talk of the town on its inauguration in 1959 . A “pioneering edifice”, hailed as “the first ful ...

Presses polytechniques et universitaires romandes2012

Cross Polarization for Dissolution Dynamic Nuclear Polarization Experiments at Readily Accessible Temperatures 1.2 < T < 4.2 K

Geoffrey Bodenhausen, Aurélien Bornet, Sami Jannin

Cross polarization can provide significant enhancements with respect to direct polarization of low-gamma nuclei such as C-13. Substantial gains in sample throughput (shorter polarization times) can be achieved by exploiting shorter build-up times tau(DNP)( ...

Springer Verlag2012

Role of the aromatic bridge on radical ions formation during reduction of diphosphaalkenes

Philip Pattison

Two molecules containing two phenylphosphaalkene moieties linked by an anthracene (1) or by a naphthalene (2) ring have been synthesized and their crystal structures have been determined. While electrochemical measurements show that these two systems are e ...

2011

Preparation, characterization and photocatalytic activity of commercial TiO2 powders co-doped by N and S

Julian Andrés Rengifo Herrera

Heterogeneous photocatalysis over TiO2 using the sunlight seems to be a promising technology for waste-water treatment and drinking water production. However, the overall efficiency of TiO2 under natural sunlight is limited to the UV-driven activity (λ < 4 ...

EPFL2009

La@C82 as a spin-active filling of SWCNTs: ESR study of magnetic and photophysical properties

László Forró, Arnaud Magrez, Duncan Thomas Lindsay Alexander, Andrzej Sienkiewicz, Katarzyna Pierzchala, Luka Ciric, Bálint Náfrádi

Electron microscopy (TEM) and electron spin resonance ESR) were applied to characterize lanthanum metallofullerene(La@C82)-filled peapods. The peapods were prepared by encapsulation of La@C82 in SWCNTs, which were obtained by laser ablation technique in th ...

2008

Effect of the electronic structure of carbon nanotubes on the selectivity of electrochemical functionalization

Klaus Kern, Marko Burghard, Kannan Balasubramanian

The functionalization of carbon nanotubes through electrochemical routes is gaining importance due to the high degree of control achievable and the ability to render the tubes with a variety of chemical and biological species. In this article, we report sy ...

2008

Application of synthetic boron-doped diamond electrodes in electrooxidation processes

Christos Comninellis, Pierre-Alain Michaud, Ilaria Duo

A review. Boron-doped diamond (BDD) thin films were grown on various substrates by chem. vapor deposition to achieve a new electrode material that possesses unique electrochem. properties. This electrodes could generate hydroxyl radicals under polarization ...

BKC2005

Electrochemical oxygen transfer reaction on synthetic boron-doped diamond thin film electrode

Synthetic boron-doped diamond thin film is a new promising anode material. Because of its properties (high anodic stability under drastic conditions and wide potential window), it is widely investigated for numerous possible electrochemical applications su ...

EPFL2004

Four-coordinate alkylidene, alkylidyne and phosphinidene complexes of vanadium: One and two-electron oxidatively-induced alpha-hydrogen abstraction reactions

Xile Hu

One electron oxidn. of the beta-Diketiminate vanadium (III) bis-neopentyl complex (Nacnac)V(CH2tBu)2 (Nacnac-=[Ar]NC(Me)CHC(Me)N[Ar], Ar=2,6-(CHMe2)2C6H3) promotes alpha-abstraction to afford the cationic four-coordinate neopentylidene vanadium complex [(N ...

2004

Electrogeneration of Hydroxyl Radicals on Boron-Doped Diamond Electrodes

Christos Comninellis, Pierre-Alain Michaud

The electrogeneration of hydroxyl radicals was studied at a synthetic B-doped diamond (BDD) thin film electrode. Spin trapping was used for detection of hydroxyl radicals with 5,5-dimethyl-1-pyrroline-N-oxide and with salicylic acid using ESR and liq. chro ...

2003

Graph Chatbot

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.