Publications related to Stille reaction

Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

Asymmetric metal-catalyzed C-H functionalization is a powerful strategy for the rapid generation of complex target molecules from simple precursors. While aryl (pseudo) halides have been used as electrophilic substrates in enantioselective Pd(0)-catalyzed ...

SWISS CHEMICAL SOC2019

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium(IV) hydride complex [K-2{U(OSi((OBu)-Bu-t)(3))(3)(mu-O)(mu-H)(2)}], 2, which displays high reductive ...

2019

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Xile Hu, Zhikun Zhang, Renyi Shi

CONSPECTUS: Ligand development plays an essential role in the advance of homogeneous catalysis. Tridentate, meridionally coordinating ligands, commonly termed pincer ligands, have been established as a privileged class of ligands in catalysis because they ...

AMER CHEMICAL SOC2019

Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers

Jérôme Waser, Matthew Wodrich, Paola Caramenti, Romain Gaëtan Tessier, Nina Declas

Enamides and enol ethers are valuable building blocks in synthetic chemistry, yet their stereoselective synthesis can be challenging. Herein, we report a new stereoselective synthesis of vinyl, aryl, alkynyl, alkyl and thio-substituted Z-enamides and enol ...

2019

A new test method of AC loss assessment for fusion conductors

Pierluigi Bruzzone, Kamil Sedlák, Boris Stepanov

The coupling currents loss for fusion conductors is frequently assessed applying a sinusoidal field sweep of fixed, small amplitude and variable frequency. From the initial slope of the loss curve, the coupling loss time constant is derived and applied in ...

ELSEVIER SCIENCE SA2019

Explore RdhK based regulatory network of organohalide respiration using a hybrid proteins strategy

Christof Holliger, Julien Maillard, Mathilde Stéphanie Willemin

Reductive dehalogenase (rdh) gene clusters are encoding proteins that enable organohalide respiring bacteria (OHRB) to couple the degradation of halogenated molecules to energy conservation. The transcription of rdh gene clusters is regulated by RdhK regul ...

2019

The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide

Paul Joseph Dyson, Simon Nussbaum, Martin Hulla, Alexy Robert Bonnin

The tandem synthesis of benzimidazole and other azoles can be achived by the N-formylation of ortho-substituted anilines followed by a cyclization reaction. However, CO2-based N-formylations with hydrosilane reducing agents are base catalyzed whereas the c ...

2019

The type IV pilus protein PilU functions as a PilT-dependent retraction ATPase

Melanie Blokesch, Sandrine Stutzmann, Candice Stoudmann, David William Adams, Jorge André Matias Pereira

Type IV pili are dynamic cell surface appendages found throughout the bacteria. The ability of these structures to undergo repetitive cycles of extension and retraction underpins their crucial roles in adhesion, motility and natural competence for transfor ...

2019

Music in premature infants enhances high-level cognitive brain networks

Dimitri Nestor Alice Van De Ville, Djalel Eddine Meskaldji, François Lazeyras

Neonatal intensive care units are willing to apply environmental enrichment via music for preterm newborns. However, no evidence of an effect of music on preterm brain development has been reported to date. Using resting-state fMRI, we characterized a circ ...

PNAS2019

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Stille reaction

Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers

Alkynylation of radicals: spotlight on the "Third Way" to transfer triple bonds

A new test method of AC loss assessment for fusion conductors

Explore RdhK based regulatory network of organohalide respiration using a hybrid proteins strategy

The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide

The type IV pilus protein PilU functions as a PilT-dependent retraction ATPase

Music in premature infants enhances high-level cognitive brain networks

Graph Chatbot

Chat with Graph Search

Alkynylation of radicals: spotlight on the "Third Way" to transfer triple bonds

Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers

The type IV pilus protein PilU functions as a PilT-dependent retraction ATPase

Music in premature infants enhances high-level cognitive brain networks

A new test method of AC loss assessment for fusion conductors

Explore RdhK based regulatory network of organohalide respiration using a hybrid proteins strategy

The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide