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The laser flash photolysis of I was studied over a wide pressure range in several bath gases. At low pressures the obsd. quantum yield for photolysis at 6943 .ANG. is independent of the gas d., whereas at higher pressures the quantum yield decreases with i ...
The photolytic cage effect was studied over a wide d. range of several bath gases in the laser flash photolysis of I2 at 694.3 nm. Particular attention was paid to measurements in the simple solvents Xe and Kr, which were compared with mol. dynamics calcns ...
The attempt to prep. hitherto unknown homopolyat. cations of sulfur by the reaction of elemental sulfur with blue S8(AsF6)2 in liq. SO2/SO2ClF, led to red (in transmitted light) crystals identified crystallog. as S8(AsF6)2. The X-ray structure of this salt ...
A simple method for the preparation of isomorphous xenon derivatives is presented. A device has been designed that allows diffraction studies on protein crystals under xenon gas pressures up to 50 x 10(5) Pa. Crystal mounting and X-ray data collection do n ...
