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The three-dimensional (3D) structure of the reaction center (RC) complex isolated from the green sulfur bacterium Chlorobium tepidum was determined from projections of negatively stained preparations by angular reconstitution. The purified complex containe ...
Formation of racemic pentose-2,4-bisphosphates is demonstrated, starting from glycolaldehyde phosphate and glyceraldehyde-2-phosphate, and induced by mixed valence double layer metal hydroxide minerals. The reactions proceed from dil. aq. reactant solns. ( ...
Solid epoxy resins are produced by catalyzed reactions of a low-mol.-wt. liq. resin (RBL) with bisphenol A (BPA). These reactions lead to solid epoxy resins that have many uses. The chain lengthening step (advancement reaction) is based on the reaction of ...
The intramolecular cyclisation of 2-hydroxyphenylacetic acid 1 into coumaran-2-one 2 was studied under both microwave irradiation and classical heating for comparison purposes. The use of a monomode oven allowed an accurate consideration of the temperature ...
The kinetics and the mechanism of the selective redn. of nitric oxides (NOx) by hydrogen is studied on a trimetallic Pt-Mo-Co/a-Al2O3 catalyst under oxidizing conditions. This system is interesting in view of an exhaust gas control of power plants or lean- ...
Metalation/trapping sequences applied to relatively inert, tert-alkyl substituted arenes tend to give poor yields unless the reagent is used in high concns. Under optimized conditions, even 1,4-bis(tert-butyl)benzene, 1,1,3,3-tetramethylindane and 1,1,2,2, ...
Target factor analysis (TFA) has been used successfully with reaction data to determine, without knowledge of reaction kinetics, the number of independent reactions and the corresponding stoichiometries. This paper analyzes the applicability of TFA techniq ...
The kinetics and the mechanism of the selective reduction of nitric oxides (NOx) by hydrogen is studied on a trimetallic Pt–Mo–Co/a-Al2O3 catalyst under oxidising conditions. This system is interesting in view of an exhaust gas control of power plants or l ...
The basic photosynthetic unit contg. the reaction center and the light-harvesting I complex (RC-LHI) of the purple non-sulfur bacterium Rhodospirillum rubrum was purified and reconstituted into two-dimensional (2D) membrane crystals. Transmission electron ...
The minimal photounit of the photosynthetic membranes of the purple non-sulfur bacterium Rhodospirillum rubrum, comprising the reaction center and the light-harvesting complex has been purified and crystd. in two dimensions in the presence of added phospho ...