Le Chatelier's principleLe Chatelier's principle (pronounced UKlə_ʃæˈtɛljeɪ or USˈʃɑːtəljeɪ), also called Chatelier's principle (or the Equilibrium Law), is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibria. The principle is named after French chemist Henry Louis Le Chatelier, and sometimes also credited to Karl Ferdinand Braun, who discovered it independently.
Water gasWater gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer [coke] with air and gasifying it with steam". The caloric yield of this is about 10% of a modern syngas plant. Further making this technology unattractive, its precursor coke is expensive, whereas syngas uses cheaper precursor, mainly methane from natural gas. Synthesis gas is made by passing steam over a red-hot carbon fuel such as coke: (ΔH = +131 kJ/mol) The reaction is endothermic, so the fuel must be continually re-heated to maintain the reaction.
GuanoGuano (Spanish from wanu) is the accumulated excrement of seabirds or bats. Guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growth. Guano was also, to a lesser extent, sought for the production of gunpowder and other explosive materials. The 19th-century seabird guano trade played a pivotal role in the development of modern input-intensive farming. The demand for guano spurred the human colonization of remote bird islands in many parts of the world.
Air separationAn air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases. The most common method for air separation is fractional distillation. Cryogenic air separation units (ASUs) are built to provide nitrogen or oxygen and often co-produce argon. Other methods such as membrane, pressure swing adsorption (PSA) and vacuum pressure swing adsorption (VPSA) are commercially used to separate a single component from ordinary air.
BiohydrogenBiohydrogen is H2 that is produced biologically. Interest is high in this technology because H2 is a clean fuel and can be readily produced from certain kinds of biomass, including biological waste. Furthermore some photosynthetic microorganisms are capable to produce H2 directly from water splitting using light as energy source. Besides the promising possibilities of biological hydrogen production, many challenges characterize this technology. First challenges include those intrinsic to H2, such as storage and transportation of an explosive noncondensible gas.
Oppau explosionThe Oppau explosion occurred on September 21, 1921, when approximately 4,500 metric tons of a mixture of ammonium sulfate and ammonium nitrate fertilizer stored in a tower silo exploded at a BASF plant in Oppau, now part of Ludwigshafen, Germany, killing 500–600 people and injuring about 2,000 more. The plant began producing ammonium sulfate in 1911, but during World War I when Germany was unable to obtain the necessary sulfur, it began to produce ammonium nitrate as well.
