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Rare-earth element

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A customized MOF-polymer composite for rapid gold extraction from water matrices

Wendy Lee Queen, Daniel Teav Sun, Shuliang Yang, Jun Li, Li Peng, Olga Syzgantseva

With the fast-growing accumulation of electronic waste and rising demand for rare metals, it is compelling to develop technologies that can promotionally recover targeted metals, like gold, from waste, a process referred to as urban mining. Thus, there is ...

AMER ASSOC ADVANCEMENT SCIENCE2023

Synthesis, isolation and application of a sila-ketenyl anion

Rosario Scopelliti, Shiori Fujimori

Ynolates or ketenyl anions, [RCCO]-, are negatively charged reactive intermediates, which can be generated in situ and used for divergent chemical transformations. Ynolates can react either at the oxygen or carbon centres or across the C-C triple bond, mak ...

Springernature2023

Separation and Recycling Potential of Rare Earth Elements from Energy Systems: Feed and Economic Viability Review

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil, Viktoria Paetzel

This review explores the potential of separating and recycling rare earth elements (REEs) from different energy conversion systems, such as wind turbines, electric vehicles batteries, or lighting devices. The REEs include 17 elements (with global productio ...

2022

Insights about inductively coupled plasma optical emission spectroscopy interferences of major rare earth elements in complex e-waste feeds

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil, Mohamed Tarik

The advent of rare earth elements (REEs) with optoelectronic properties has shifted the technology paradigm from digital to a smart and hybrid world. Their substantial uses also resulted in a large piling up of e-waste. Therefore, e-waste is now a lucrativ ...

2022

Opportunities in Critical Rare Earth Metal Recycling Value Chains for Economic Growth with Sustainable Technological Innovations

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil

Rare earth elements (REEs) are often referred to as the industrial vitamins and the key drivers of the industry 4.0 revolution. The current global supply chain of REEs for green and high-tech applications with more than 220 metric kilotons per year involve ...

2022

Magnetism and metal-organic self-assembly of rare-earth atoms on decoupling layers

Sébastien Reynaud

This thesis presents investigations of magnetic and structural properties of two dimensional metal-organic frameworks and of single atoms, both adsorbed on decoupling layers grown on metal surfaces, with focus on rare earth elements. We first report on a ...

EPFL2022

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Chiral Diimine Complexes of Earth-Abundant Transition Metals for Asymmetric Catalysis

Elena Braconi

The application of Earth-abundant metals in asymmetric catalysis is key to transition towards a more sustainable chemistry. In particular, expanding the library of redox-active ligands capable of supporting Earth-abundant metals is essential in order to re ...

EPFL2022

Exploring Photoredox-Catalyzed (Re)functionalizations with Core-Modified Benziodoxolones

Jérôme Waser, Franck Le Vaillant, Stephanie Grace Elizabeth Amos

Alkynes and nitriles are valuable building blocks in organic synthesis and also have multiple applications in chemical biology and materials science. Due to the high availability of tertiary alcohols, developing methods for their conversion into alkynes an ...

2022

Long Spin Lifetime in Rare-Earth Single-Atom Magnets at Surfaces

Boris Sorokin

Further miniaturisation of magnetic storage devices requires an advent of new types of magnets, since classical ferromagnetic materials show lack of remanence at nano- and subnanoscale. A single atom can represent the smallest possible bit of information. ...

EPFL2022

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Synthesis, isolation and application of a sila-ketenyl anion

Rosario Scopelliti, Shiori Fujimori

Springernature2023

Separation and Recycling Potential of Rare Earth Elements from Energy Systems: Feed and Economic Viability Review

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil, Viktoria Paetzel

2022

Insights about inductively coupled plasma optical emission spectroscopy interferences of major rare earth elements in complex e-waste feeds

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil, Mohamed Tarik

2022

Opportunities in Critical Rare Earth Metal Recycling Value Chains for Economic Growth with Sustainable Technological Innovations

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil

2022