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Concept
Monolayer
Summary
A monolayer is a single, closely packed layer of atoms, molecules, or cells. In some cases it is referred to as a self-assembled monolayer. Monolayers of layered crystals like graphene and molybdenum disulfide are generally called 2D materials.
A Langmuir monolayer or insoluble monolayer is a one-molecule thick layer of an insoluble organic material spread onto an aqueous subphase in a Langmuir-Blodgett trough. Traditional compounds used to prepare Langmuir monolayers are amphiphilic materials that possess a hydrophilic headgroup and a hydrophobic tail. Since the 1980s a large number of other materials have been employed to produce Langmuir monolayers, some of which are semi-amphiphilic, including polymeric, ceramic or metallic nanoparticles and macromolecules such as polymers. Langmuir monolayers are extensively studied for the fabrication of Langmuir-Blodgett film (LB films), which are formed by transferred monolayers on a solid substrate. A Gibbs monolayer or soluble monolayer is a monolayer formed by a compound that is soluble in one of the phases separated by the interface on which the monolayer is formed.
The monolayer formation time or monolayer time is the length of time required, on average, for a surface to be covered by an adsorbate, such as oxygen sticking to fresh aluminum. If the adsorbate has a unity sticking coefficient, so that every molecule which reaches the surface sticks to it without re-evaporating, then the monolayer time is very roughly:
where t is the time and P is the pressure. It takes about 1 second for a surface to be covered at a pressure of 300 μPa (2×10−6 Torr).
A Langmuir monolayer can be compressed or expanded by modifying its area with a moving barrier in a Langmuir film balance. If the surface tension of the interface is measured during the compression, a compression isotherm is obtained. This isotherm shows the variation of surface pressure (, where is the surface tension of the interface before the monolayer is formed) with the area (the inverse of surface concentration ).
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