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A water wheel is a machine for converting the energy of flowing or falling water into useful forms of power, often in a watermill. A water wheel consists of a wheel (usually constructed from wood or metal), with a number of blades or buckets arranged on the outside rim forming the driving car. Water wheels were still in commercial use well into the 20th century but they are no longer in common use. Uses included milling flour in gristmills, grinding wood into pulp for papermaking, hammering wrought iron, machining, ore crushing and pounding fibre for use in the manufacture of cloth. Some water wheels are fed by water from a mill pond, which is formed when a flowing stream is dammed. A channel for the water flowing to or from a water wheel is called a mill race. The race bringing water from the mill pond to the water wheel is a headrace; the one carrying water after it has left the wheel is commonly referred to as a tailrace. Waterwheels were used for various purposes from things

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Origin of the Strong Interaction between Polar Molecules and Copper(II) Paddle-Wheels in Metal Organic Frameworks

Daniele Ongari, Berend Smit, Davide Tiana

The copper paddle-wheel is the building unit of many metal organic frameworks. Because of the ability of the copper cations to attract polar molecules, copper paddle-wheels are promising for carbon dioxide adsorption and separation. They have therefore been studied extensively, both experimentally and computationally. In this work we investigate the copper-CO2 interaction in HKUST-1 and in two different cluster models of HKUST-1: monocopper Cu(formate)(2) and dicopper Cu-2(formate)(4). We show that density functional theory methods severely underestimate the interaction energy between copper paddle-wheels and CO2, even including corrections for the dispersion forces. In contrast, a multireference wave function followed by perturbation theory to second order using the CASPT2 method correctly describes this interaction. The restricted open-shell Moller-Plesset 2 method (ROS-MP2, equivalent to (2,2) CASPT2) was also found to be adequate in describing the system and used to develop a novel force field. Our parametrization is able to predict the experimental CO2 adsorption isotherms in HKUST-1, and it is shown to be transferable to other copper paddle-wheel systems.

American Chemical Society2017

Effect of building overtopping on induced loads during extreme hydrodynamic events

Ioan Nistor, Michael Pfister, Anton Schleiss, Davide Wüthrich

Tsunamis, impulse-waves and dam-break waves have affected humanity in recent decades and the construction of vertical shelters can provide safety to people. However, for non-critical infrastructures, typically residential houses of lower height, overtopping is accepted during such events. This study experimentally quantifies the effect of building overtopping, i.e. water flowing over the roof, on the resulting loading process. Both surges and bores were investigated and the impact against buildings with two different heights was assessed. Detailed measurements of forces and moments allowed key differences to be captured between the scenarios with and without overtopping. Results showed that overtopping induced higher downstream water depths, leading to lower horizontal forces and a reduced resistance coefficient. Furthermore, cantilever arm, moment and impulse values were constantly lower in case of overtopping. Finally, this study presents an innovative methodology to assess the main loading features of buildings subject to overtopping, supporting engineers to design safer resilient structures.

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