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Reaction of anilines, primary and secondary aliph. amines with cyclopropylboronic acid in dichloroethane in the presence of Cu(OAc)2 (1 equiv.), 2,2'-bipyridine (1 equiv.) and sodium carbonate or sodium bicarbonate (2 equiv.) under air atm. afforded the co ...
This work investigates sulfate attack in complex sulfate environments by exposing different binder types to various sulfate solutions and comparing predicted phase and volume changes with experimental data. The most important aspects of this work can be gr ...
Hydrogenation of bicarbonates in water: By using a ruthenium-based catalytic system hydrogenation of sodium bicarbonate was achieved in water in comparable high TONs and yields. The hydrogenation of sodium bicarbonate takes place with the catalytic system ...
Lack of improved drinking water sources contributes a lot to many waterborne diseases caused by pathogens which include viruses, protozoa, bacteria or worms. It is essential to develop and promote treatment methods in order to provide pathogen-free safe dr ...
Sonochemical elimination of organic pollutants can take place through two degradation pathways. Molecules with relatively large Henry’s law constants will be incinerated inside the cavitation bubble, while nonvolatile molecules with low Henry’s law constan ...
This work deals with the ultrasonic degradation (800 kHz) of crystal violet (CV) under different experimental conditions. The effects of saturating gas (argon, carbon dioxide and air), CV concentration (2.45-1225 mu mol L-1), pH (3-9) and power (20-80 W) w ...
Enhanced reductive dehalogenation is an attractive treatment technology for in situ remediation of chlorinated solvent DNAPL source areas. Reductive dehalogenation is an acid-forming process with hydrochloric acid and also organic acids from fermentation o ...
It has been suggested already more than 60 years ago to use polarized nuclei in particle scattering experiments1, but only with the discovery of the solid effect dynamic nuclear polarization process2 the realisation of polarized solid targets became possib ...
The water soluble ruthenium(II) complex [RuCl2(PTA)([9]aneS3)] (PTA = 1,3,5-triaza-7-phosphadamantane, [9]aneS3 = 1,4,7-trithiacyclononane) catalyzes the hydrogenation of CO2 and bicarbonate in aqueous solution. ...
Methanogenesis from main methane precursors H2/CO2 and acetate was investigated in a temperature range of 2–70 °C using sediments from Lake Baldegg, Switzerland. Psychrophilic, psychrotrophic, mesophilic, and thermophilic methanogenic microbial communities ...