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Concept
Phase-field model
Summary
A phase-field model is a mathematical model for solving interfacial problems. It has mainly been applied to solidification dynamics, but it has also been applied to other situations such as viscous fingering, fracture mechanics, hydrogen embrittlement, and vesicle dynamics.
The method substitutes boundary conditions at the interface by a partial differential equation for the evolution of an auxiliary field (the phase field) that takes the role of an order parameter. This phase field takes two distinct values (for instance +1 and −1) in each of the phases, with a smooth change between both values in the zone around the interface, which is then diffuse with a finite width. A discrete location of the interface may be defined as the collection of all points where the phase field takes a certain value (e.g., 0).
A phase-field model is usually constructed in such a way that in the limit of an infinitesimal interface width (the so-called sharp interface limit) the correct interfacial dynamics are recovered. This approach permits to solve the problem by integrating a set of partial differential equations for the whole system, thus avoiding the explicit treatment of the boundary conditions at the interface.
Phase-field models were first introduced by Fix and Langer, and have experienced a growing interest in solidification and other areas.
Phase-field models are usually constructed in order to reproduce a given interfacial dynamics. For instance, in solidification problems the front dynamics is given by a diffusion equation for either concentration or temperature in the bulk and some boundary conditions at the interface (a local equilibrium condition and a conservation law), which constitutes the sharp interface model.
A number of formulations of the phase-field model are based on a free energy function depending on an order parameter (the phase field) and a diffusive field (variational formulations). Equations of the model are then obtained by using general relations of statistical physics.
Official source
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