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This paper reports the synthesis of rationally designed polypeptides that catalyze the decarboxylation of oxaloacetate via an imine intermediate. The authors det. the secondary structures of the polypeptides by two-dimensional NMR spectroscopy. The authors ...
Azides are building blocks of increasing importance in synthetic chemistry, chemical biology, and materials science. Azidobenziodoxolone (ABX, Zhdankin reagent) is a valuable azide source, but its safety profile has not been thoroughly established. Herein, ...
