Leaching is the process of a solute becoming detached or extracted from its carrier substance by way of a solvent. Leaching is a naturally occurring process which scientists have adapted for a variety of applications with a variety of methods. Specific extraction methods depend on the soluble characteristics relative to the sorbent material such as concentration, distribution, nature, and size. Leaching can occur naturally seen from plant substances (inorganic and organic), solute leaching in soil, and in the decomposition of organic materials. Leaching can also be applied affectedly to enhance water quality and contaminant removal, as well as for disposal of hazardous waste products such as fly ash, or rare earth elements (REEs). Understanding leaching characteristics is important in preventing or encouraging the leaching process and preparing for it in the case where it is inevitable. In an ideal leaching equilibrium stage, all the solute is dissolved by the solvent, leaving the carrier of the solute unchanged. The process of leaching however is not always ideal, and can be quite complex to understand and replicate, and often different methodologies will produce different results. There are many types of leaching scenarios; therefore, the extent of this topic is vast. In general, however, the three substances can be described as: a carrier, substance A; a solute, substance B; and a solvent, substance C. Substance A and B are somewhat homogenous in a system prior to the introduction of substance C. At the beginning of the leaching process, substance C will work at dissolving the surficial substance B at a fairly high rate. The rate of dissolution will decrease substantially once it needs to penetrate through the pores of substance A in order to continue targeting substance B. This penetration can often lead to dissolution of substance A, or the product of more than one solute, both unsatisfactory if specific leaching is desired.
Annapaola Parrilli, Ludger Weber, Caroline Hain, Alberto Ortona, Manoj Kondibhau Naikade