Concept
Disproportionation
Related publications (34)
Gas/Surface reactions probed by reflection absorption infrared spectroscopy
In my thesis, I present an investigation of the dissociation reactions of gas phase molecules on single crystal metal surfaces studied by a molecular beam in combination with Reflection Absorption Infrared Spectroscopy (RAIRS). Two gas/surface systems were ...
EPFL2023Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity
The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...
EPFL2022Active anaerobic methane oxidation and sulfur disproportionation in the deep terrestrial subsurface
Rizlan Bernier-Latmani, Manon Frutschi, Emma Bell, Chen Qian
Microbial life is widespread in the terrestrial subsurface and present down to several kilometers depth, but the energy sources that fuel metabolism in deep oligotrophic and anoxic environments remain unclear. In the deep crystalline bedrock of the Fennosc ...
2022Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands
Rosario Scopelliti, Marinella Mazzanti, Marta Falcone, Nadir Jori
The synthesis, structure, and reactivity with CO2 and CS2 of new U(IV) complexes with a redox-active Schiff base are reported. The reaction of UI3 with the heptadentate Schiff base ligand 2,2',2 ''-tris(salicylideneimino)-triethylamine (trensal) did not le ...
AMER CHEMICAL SOC2020Contaminant loading and competitive access of Pb, Zn and Mn(III) to vacancy sites in biogenic MnO2
Louise Helene Soegaard Jensen, Jasquelin Peña
The scavenging properties of MnO2 are largely attributed to sorption on layer vacancy sites. However, co-occurrence of Mn(II, III) with MnO2 can change mineral reactivity by modifying its Mn(III) content or number of free vacancy sites. These processes are ...
2018Equilibria and Speciation of Chloramines, Bromamines, and Bromochloramines in Water
Jeremy Samuel Arey, Daniela Trogolo
The stabilities and speciation of the halamines in water are difficult to characterize experimentally. We provide theoretical estimates of aqueous standard free energies of formation for inorganic chloramines, bromamines, and bromochloramines, based on hig ...
Amer Chemical Soc2017