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Pure and K-doped vanadia/titania prepared by different methods have been studied in order to elucidate the role of vanadia species (monomeric, polymeric, bulk) in catalytic toluene partial oxidation. The ratio of different vanadia species was controlled by ...
The homogeneous catalytic system, based on water-soluble ruthenium(II)– TPPTS catalyst (TPPTS = meta-trisulfonated triphenylphosphine), selectively decomposes HCOOH into H2 and CO2 in aqueous solution. Although this reaction results in only two gas product ...
A new one-pot synthesis of sulfoxides is presented. It involves the bora-ene reaction of sulfur dioxide and prop-2-ene-1-boronic esters, giving mixed anhydrides of sulfinic and boric acids. The latter react chemoselectively at the sulfur center with Grigna ...
Transactions are commonly described as being ACID: All-or-nothing, Consistent, Isolated and Durable. However, although these words convey a powerful intuition, the ACID properties have never been given a precise semantics in a way that disentangles each pr ...
Enhanced reductive dehalogenation is an attractive in-situ treatment technology for chlorinated contaminants. The process includes two acid-forming microbial reactions, that is, fermentation of an organic substrate to hydrogen and short chain fatty acids f ...
Major explosive volcanic eruptions inject gases and ash particles into the stratosphere, resulting in significant impacts on ozone and climate. Here we report on fast and sensitive in situ measurements of sulfur dioxide (SO2), hydrochloric acid (HCl), and ...
Electrochemical and friction measurements during unidirectional sliding tests are used to monitor and to evaluate the tribocorrosion behavior of a passivating material. Tribocorrosion is the interplay between chemical, electrochemical, and mechanical proce ...
Femtosecond laser irradiation has various noticeable effects on fused silica. Of particular interest, pulses with energy levels below the ablation threshold can locally increase the refractive index and the material etching selectivity to hydrofluoric acid ...
Boron-doped diamond electrodes, both as-grown and polarized anodically under different conditions, were prepd. in order to study the chem. and electrochem. changes of diamond and clarify the role played by the surface-state d. Many different treatments wer ...
A thermodynamic model, the Gibbs Free-Energy Minimization model (GFEMN), was used to simulate the partitioning of PM2.5 nitrate aerosol and nitric acid using highly time-resolved inorganic measurements collected at the Pittsburgh Air Quality Study during J ...
