Publications related to Phosphorus trichloride

The Intricate Chemistry of Cobalt(II) Halides and Bis(diphenylphosphanyl)ethane

Rosario Scopelliti, Kay Severin, Heron Vrubel, Gregor Kiefer

Phosphane complexes of the putative formula [CoX2(dppe)] [X = Cl, Br, I; dppe = bis(diphenylphosphanyl)ethane] are frequently used catalyst precursors in cobalt-catalyzed reactions. Despite their widespread use, these complexes have not been structurally c ...

Wiley-Blackwell2013

Tuning the Chemoselectivity of Rh Nanoparticle Catalysts by Site-Selective Poisoning with Phosphine Ligands: The Hydrogenation of Functionalized Aromatic Compounds

Paul Joseph Dyson, Gabor Laurenczy, Ning Yan, Weijia Gan, Dennis Snelders

The hydrogenation of phenylacetone to cyclohexylacetone, in which the aromatic ring is selectively reduced in preference to the carbonyl group, has been achieved with chemoselectivities exceeding 90%. The catalyst (precatalyst) used to achieve this transfo ...

2012

Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents

Paul Joseph Dyson, Catherine Marie Amélie Clavel

Tridentate cycloplatinated thiosemicarbazone complexes have been prepared from a biologically significant ligand, 3,4-dichloroacetophenone thiosemicarbazone (1). The tetranuclear complex 2 was prepared by reaction of the ligand with K-2[PtCl4]. Two mononuc ...

Amer Chemical Soc2012

Metal Phosphorus Complexes as Antitumor Agents

Paul Joseph Dyson, Alexey Nazarov

Phosphorus-based ligands are an extremely important class of ligand and they have found many applications, especially in homogeneous catalysis. In addition, a phosphine ligand is found in a gold drug used to treat rheumatoid arthritis. Since metal compound ...

Springer Netherlands2011

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Angela Casini, Catherine Marie Amélie Clavel, elena vergara

A series of thiolate gold(I) derivatives bearing water soluble phosphanes - namely sodium triphenylphosphane monosulfonate (TPPMS), sodium triphenylphosphane trisulfonate (TPPTS), 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosp ...

2011

Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

Pierre Vogel, Chandra Mouleeswara Rao Volla

2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium- catalyzed C–C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl ...

2009

Growth modification of hematite by phosphonate additives

Heinrich Hofmann, Paul Bowen, Ulrich Aschauer

The hydroxylated surface structures of seven morphologically important crystallographic surfaces of hematite were calculated allowing the determination of the surface energies and, consequently,the hematite equilibrium morphology. The docking of two organi ...

2008

Study of n- and p-type dopants activation and dopants behavior with respect to annealing conditions in silicon germanium-on-insulator (SGOI)

Mihai Adrian Ionescu, Jyotshna Bhandari

We have investigated the p- and n-type dopants in thin SGOI (20 nm) material obtained by Ge enrichment. The samples are doped with either BF2 or arsenic or phosphorus and then annealed with either a spike or a 15 s rapid thermal annealing in a temperature ...

2008

In vitro anticancer activity and biologically relevant metabolization of organometallic ruthenium complexes with carbohydrate-based ligands

Paul Joseph Dyson, Christian Hartinger, Alexey Nazarov, Olivier Pierre Zava, Michael Groessl, Frédéric Schmitt, Muhammad Hanif

The synthesis and in vitro anticancer activity of dihalo(η6-p-cymene)(3,5,6-bicyclophosphite-α-D-glucofuranoside)ruthenium(II) complexes are described. The compds. were characterized by NMR spectroscopy and ESI mass spectrometry, and the mol. structures of ...

2008

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Phosphorus trichloride

The Intricate Chemistry of Cobalt(II) Halides and Bis(diphenylphosphanyl)ethane

Tuning the Chemoselectivity of Rh Nanoparticle Catalysts by Site-Selective Poisoning with Phosphine Ligands: The Hydrogenation of Functionalized Aromatic Compounds

Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents

Metal Phosphorus Complexes as Antitumor Agents

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Atmospheric acidification of mineral aerosols: A source of bioavailable phosphorus for the oceans

Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

Growth modification of hematite by phosphonate additives

Study of n- and p-type dopants activation and dopants behavior with respect to annealing conditions in silicon germanium-on-insulator (SGOI)

In vitro anticancer activity and biologically relevant metabolization of organometallic ruthenium complexes with carbohydrate-based ligands

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Atmospheric acidification of mineral aerosols: A source of bioavailable phosphorus for the oceans

Metal Phosphorus Complexes as Antitumor Agents

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

Growth modification of hematite by phosphonate additives

The Intricate Chemistry of Cobalt(II) Halides and Bis(diphenylphosphanyl)ethane

Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents

In vitro anticancer activity and biologically relevant metabolization of organometallic ruthenium complexes with carbohydrate-based ligands

Study of n- and p-type dopants activation and dopants behavior with respect to annealing conditions in silicon germanium-on-insulator (SGOI)

Tuning the Chemoselectivity of Rh Nanoparticle Catalysts by Site-Selective Poisoning with Phosphine Ligands: The Hydrogenation of Functionalized Aromatic Compounds