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The kinetics of the oxidn. of nitrite to nitrate by peroxynitrous acid at pH 5.2 is best described by the rate law kobs = kiso + k'[NO2-] + k''[NO2-]2, in which the peroxynitrous acid isomerization rate const. kiso = (1.10 +- 0.05) s-1, k' = (3.2 +- 0.1) M ...
We consider a queuing problem in which both the service rate of a finite-buffer queue and its rate of arrivals are functions of the same partially observed Markov chain. Basic performance indices of this device, such as long term throughput and loss rates, ...
The theory of high rate lossy source coding is well developed both with respect to the practice of quantization and its fundamental rate distortion limits. But many modern compression systems for natural signals such as audio and images operate at lower ra ...
A method for the online calcn. of conversion rates and yield coeffs. under dynamic process conditions was developed. The method is based on cumulated mass balances using a moving av. method. Elemental balances were used to test the measured cumulated quant ...
New NMR (NMR) methods are described for the measurement of cross-correlation rates of zero- and double-quantum coherences involving two nitrogen nuclei belonging to successive amino acids in proteins and peptides. Rates due to the concerted fluctuations of ...
This paper derives an expression for the optimal error nonlinearity in
adaptive filter design. Using an energy conservation relation, and some typical assumptions, the choice of the error function is optimized by minimizing the mean-square deviation subj ...
The development of the interfacial bond strength as a function of bonding conditions has been investigated in two representative semicrystalline thermoplastics, isotactic polypropylene and polyamide 12. If one side of the interface is well above the meltin ...
We give a complete characterization of affine term structure models based on a general nonnegative Markov short rate process. This applies to the classical CIR model but includes as well short rate processes with jumps.We provide a link to the theory of br ...
In this article we discuss Markovian term structure models in discrete time and with continuous state space. More precisely we are concerned with the structural properties of such models if one has the Markov property for a part of the forward curve. We in ...
A balanced supplementation method was applied to develop a serum and protein- free medium supporting hybridoma cell batch culture. The aim was to improve systematically the initial formulation of the medium to prevent limitations due to unbalanced concns. ...
