Publications related to Ligand

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

Development of Site-Specific Mg2+-RNA Force Field Parameters: A Dream or Reality? Guidelines from Combined Molecular Dynamics and Quantum Mechanics Simulations

Ursula Röthlisberger, Giulia Palermo, Lorenzo Casalino

The vital contribution of Mg2+ ions to RNA biology is challenging to dissect at the experimental level. This calls for the integrative support of atomistic simulations, which at the classical level are plagued by limited accuracy. Indeed, force fields intr ...

2017

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone, Rory Patrick Kelly

Herein, we report the synthesis and characterisation of the first terminal uranium(V) sulfide and a related UV trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound UV imido comple ...

2017

Potential energy-driven spin manipulation via a controllable hydrogen ligand

Klaus Kern, Markus Ternes

Spin-bearing molecules can be stabilized on surfaces and in junctions with desirable properties, such as a net spin that can be adjusted by external stimuli. Using scanning probes, initial and final spin states can be deduced from topographic or spectrosco ...

Amer Assoc Advancement Science2017

Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C−H Alkylation of Arenes: Iminoarylation of Alkenes

Qian Wang, Jieping Zhu, Xu Bao

A palladium-catalyzed reaction of g,d-unsaturated oxime esters with oxadiazoles afforded dihydropyrroles in good to excellent yields through an intramolecular iminopalladation/intermolecular direct heteroarene C-H alkylation cascade. This unprecedented imi ...

Wiley-Blackwell2017

Colloidal nanocrystals for photoelectrochemical and photocatalytic water splitting

Raffaella Buonsanti, Anna Loiudice, Chethana Janardhana Gadiyar

Colloidal nanocrystals (NCs) are among the most modular and versatile nanomaterial platforms for studying emerging phenomena in different fields thanks to their superb compositional and morphological tunability. A promising, yet challenging, application in ...

2017

Highly selective immobilized bimetallic Ni-Au nanoparticle catalyst for the partial hydrogenation of m-dinitrobenzene

Paul Joseph Dyson, Lioubov Kiwi, Fernando Cardenas Lizana, Daniel André Samuel Lamey, Oliver Anthony Beswick

Transition metal nanoparticles (NPs) are extensively used as catalysts for a wide and diverse range of organic transformations when immobilized on appropriate solid supports. We describe the development of a highly active and highly selective heterogeneous ...

Elsevier Science Bv2017

PdII2L4-type coordination cages up to three nanometers in size

Rosario Scopelliti, Kay Severin, Suzanne Maria Jansze, Matthew David Wise

The utilization of large ligands in coordination-based self-assembly represents an attractive strategy for the construction of supramolecular assemblies more than two nanometers in size. However, the implementation of this strategy is hampered by the fact ...

2017

Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties

Berend Smit, Cory Matthew Simon, Efrem Daniel Braun

Some nanoporous, crystalline materials possess dynamic constituents, for example, rotatable moieties. These moieties can undergo a conformation change in response to the adsorption of guest molecules, which qualitatively impacts adsorption behavior. We pos ...

National Academy of Sciences2017

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Ligand

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Development of Site-Specific Mg2+-RNA Force Field Parameters: A Dream or Reality? Guidelines from Combined Molecular Dynamics and Quantum Mechanics Simulations

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Potential energy-driven spin manipulation via a controllable hydrogen ligand

Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C−H Alkylation of Arenes: Iminoarylation of Alkenes

Colloidal nanocrystals for photoelectrochemical and photocatalytic water splitting

Highly selective immobilized bimetallic Ni-Au nanoparticle catalyst for the partial hydrogenation of m-dinitrobenzene

PdII2L4-type coordination cages up to three nanometers in size

Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties

Phage Selection of Cyclic Peptides for Application in Research and Drug Development

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Chat with Graph Search

Highly selective immobilized bimetallic Ni-Au nanoparticle catalyst for the partial hydrogenation of m-dinitrobenzene

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Development of Site-Specific Mg2+-RNA Force Field Parameters: A Dream or Reality? Guidelines from Combined Molecular Dynamics and Quantum Mechanics Simulations

Potential energy-driven spin manipulation via a controllable hydrogen ligand

Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C−H Alkylation of Arenes: Iminoarylation of Alkenes

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Colloidal nanocrystals for photoelectrochemical and photocatalytic water splitting

Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties

PdII2L4-type coordination cages up to three nanometers in size

Phage Selection of Cyclic Peptides for Application in Research and Drug Development